Home / Publications / Highly diastereocelective one-pot four-component coupling of p-TolSCI, 1-methoxycycloalkene, methyl vinyl ether and a carbon nucleophile leading to the synthesis of polyfunctional compounds

Highly diastereocelective one-pot four-component coupling of p-TolSCI, 1-methoxycycloalkene, methyl vinyl ether and a carbon nucleophile leading to the synthesis of polyfunctional compounds

Margarita Ivanovna Lazareva 1
Margarita Ivanovna Lazareva
, 
Yuri Konstantinovich Kryschenko 2
Yuri Konstantinovich Kryschenko
, 
Ron Caple 2
Ron Caple
, 
Victor G YoungJr 3
Victor G YoungJr
, 
William Arturovich Smit 1
William Arturovich Smit
10.1070/MC1999v009n01ABEH001044
Published 1999-02-16
Communication , Volume 9, Issue 1, 24-25
3
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Lazareva M. I. et al. Highly diastereocelective one-pot four-component coupling of p-TolSCI, 1-methoxycycloalkene, methyl vinyl ether and a carbon nucleophile leading to the synthesis of polyfunctional compounds // Mendeleev Communications. 1999. Vol. 9. No. 1. pp. 24-25.
GOST all authors (up to 50) Copy
Lazareva M. I., Kryschenko Y. K., Caple R., YoungJr V. G., Smit W. A. Highly diastereocelective one-pot four-component coupling of p-TolSCI, 1-methoxycycloalkene, methyl vinyl ether and a carbon nucleophile leading to the synthesis of polyfunctional compounds // Mendeleev Communications. 1999. Vol. 9. No. 1. pp. 24-25.
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TY - JOUR
DO - 10.1070/MC1999v009n01ABEH001044
UR - https://mendcomm.colab.ws/publications/10.1070/MC1999v009n01ABEH001044
TI - Highly diastereocelective one-pot four-component coupling of p-TolSCI, 1-methoxycycloalkene, methyl vinyl ether and a carbon nucleophile leading to the synthesis of polyfunctional compounds
T2 - Mendeleev Communications
AU - Lazareva, Margarita Ivanovna
AU - Kryschenko, Yuri Konstantinovich
AU - Caple, Ron
AU - YoungJr, Victor G
AU - Smit, William Arturovich
PY - 1999
DA - 1999/02/16
PB - Mendeleev Communications
SP - 24-25
IS - 1
VL - 9
ER -
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@article{1999_Lazareva,
author = {Margarita Ivanovna Lazareva and Yuri Konstantinovich Kryschenko and Ron Caple and Victor G YoungJr and William Arturovich Smit},
title = {Highly diastereocelective one-pot four-component coupling of p-TolSCI, 1-methoxycycloalkene, methyl vinyl ether and a carbon nucleophile leading to the synthesis of polyfunctional compounds},
journal = {Mendeleev Communications},
year = {1999},
volume = {9},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1999v009n01ABEH001044},
number = {1},
pages = {24--25},
doi = {10.1070/MC1999v009n01ABEH001044}
}
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Lazareva, Margarita Ivanovna, et al. “Highly diastereocelective one-pot four-component coupling of p-TolSCI, 1-methoxycycloalkene, methyl vinyl ether and a carbon nucleophile leading to the synthesis of polyfunctional compounds.” Mendeleev Communications, vol. 9, no. 1, Feb. 1999, pp. 24-25. https://mendcomm.colab.ws/publications/10.1070/MC1999v009n01ABEH001044.

Abstract

An one-pot TiCl4 initiated assemblage of polyfunctional compounds via a sequential coupling of p-TolSCl, 1-methoxycycloalkene, methyl vinyl ether and Sn- or Si-capped carbon nucleophile is shown to proceed with high diastereoselectivity at all newly created chiral centres.

References

1.
Hayford A., Lovdahl M., Lazareva M.I., Kryschenko Y.K., Johnson T., Dilman A.D., Smoliakova I.P., Caple R., Smit W.A.
Mendeleev Communications, 1997
2.
Controlled one-pot sequence of three AdE reactions as a novel protocol for the synthesis of polyfunctional compounds
Lazareva M.I., Kryschenko Y.K., Hayford A., Lovdahl M., Caple R., Smit W.A.
Tetrahedron Letters, 1998
3.
10.1070/MC1999v009n01ABEH001044_bib3
Lazareva
Izv. Akad. Nauk, Ser. Khim., 1998