Home / Publications / Reaction of N,N-dimethylaniline with 1,5-diferrocenyl-3-methyl-2,4-trimethylene-penta-1,4-dienyl carbocation. A nonsynchronous cationic cyclodimerization mechanism in conjugated dienes

Reaction of N,N-dimethylaniline with 1,5-diferrocenyl-3-methyl-2,4-trimethylene-penta-1,4-dienyl carbocation. A nonsynchronous cationic cyclodimerization mechanism in conjugated dienes

Elena Ivanovna Klimova 1
Elena Ivanovna Klimova
, 
Tatiana Klimova-Berestneva 1
Tatiana Klimova-Berestneva
, 
Marcos Martinez Garcia 2
Marcos Martinez Garcia
, 
Lena Ruiz-Ramirez 1
Lena Ruiz-Ramirez
10.1070/MC1998v008n06ABEH001015
Published 1998-12-16
Communication , Volume 8, Issue 6, 233-236
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Klimova E. I. et al. Reaction of N,N-dimethylaniline with 1,5-diferrocenyl-3-methyl-2,4-trimethylene-penta-1,4-dienyl carbocation. A nonsynchronous cationic cyclodimerization mechanism in conjugated dienes // Mendeleev Communications. 1998. Vol. 8. No. 6. pp. 233-236.
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Klimova E. I., Klimova-Berestneva T., Martinez Garcia M., Ruiz-Ramirez L. Reaction of N,N-dimethylaniline with 1,5-diferrocenyl-3-methyl-2,4-trimethylene-penta-1,4-dienyl carbocation. A nonsynchronous cationic cyclodimerization mechanism in conjugated dienes // Mendeleev Communications. 1998. Vol. 8. No. 6. pp. 233-236.
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TY - JOUR
DO - 10.1070/MC1998v008n06ABEH001015
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n06ABEH001015
TI - Reaction of N,N-dimethylaniline with 1,5-diferrocenyl-3-methyl-2,4-trimethylene-penta-1,4-dienyl carbocation. A nonsynchronous cationic cyclodimerization mechanism in conjugated dienes
T2 - Mendeleev Communications
AU - Klimova, Elena Ivanovna
AU - Klimova-Berestneva, Tatiana
AU - Martinez Garcia, Marcos
AU - Ruiz-Ramirez, Lena
PY - 1998
DA - 1998/12/16
PB - Mendeleev Communications
SP - 233-236
IS - 6
VL - 8
ER -
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@article{1998_Klimova,
author = {Elena Ivanovna Klimova and Tatiana Klimova-Berestneva and Marcos Martinez Garcia and Lena Ruiz-Ramirez},
title = {Reaction of N,N-dimethylaniline with 1,5-diferrocenyl-3-methyl-2,4-trimethylene-penta-1,4-dienyl carbocation. A nonsynchronous cationic cyclodimerization mechanism in conjugated dienes},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n06ABEH001015},
number = {6},
pages = {233--236},
doi = {10.1070/MC1998v008n06ABEH001015}
}
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Klimova, Elena Ivanovna, et al. “Reaction of N,N-dimethylaniline with 1,5-diferrocenyl-3-methyl-2,4-trimethylene-penta-1,4-dienyl carbocation. A nonsynchronous cationic cyclodimerization mechanism in conjugated dienes.” Mendeleev Communications, vol. 8, no. 6, Dec. 1998, pp. 233-236. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n06ABEH001015.

Abstract

Reaction of the 1,5-diferrocenyl-3-methyl-2,4-trimethylenepenta-1,4-dienyl tetrafluoroborate cation with N,N-dimethylaniline affords a mixture of products from the alkylation of N,N-dimethylaniline at the para-position by monomeric and linear and cyclic dimeric carbocations along with linear and cyclic dimers of 1,3-diferrocenylmethylene-2-methylenecyclohexane. These results confirm and illustrate a nonsynchronous cationic cyclodimerization mechanism for ferrocenylbuta-1,3-dienes.

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