Abstract
Methane, ethane and ethylene are oxidised by hydrogen peroxide in aqueous solutions at room temperature and atmospheric pressure in the presence of peroxocomplexes of copper(II) hydroxide; the reaction presumably proceeds by a non-radical mechanism.
References
1.
Kovalenko G.A.
Russian Chemical Reviews,
1996
2.
Shu L., Nesheim J.C., Kauffmann K., Münck E., Lipscomb J.D., Que L.
Science,
1997
3.
Shin W., Sundaram U.M., Cole J.L., Zhang H.H., Hedman B., Hodgson K.O., Solomon E.I.
Journal of the American Chemical Society,
1996
4.
Vigato P.A., Tamburini S., Fenton D.E.
Coordination Chemistry Reviews,
1990
5.
10.1070/MC1998v008n06ABEH001013_bib5
Elizarova
Kinet. Katal.,
1998
6.
10.1070/MC1998v008n06ABEH001013_bib6
Karyakin
Chistye khimicheskie veshchestva (Pure Chemical Substances),
1974
7.
10.1070/MC1998v008n06ABEH001013_bib7
Charlot
Les Methodes de la Chimie Analytique. Analyse Quantitative Minerale,
1961
8.
G. L. Elizarova, L. G. Matvienko, O. L. Ogorodnikova and V. N. Parmon, Kinet. Katal., submitted.
9.
Grant W.M.
Analytical Chemistry,
1948
10.