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Synthesis of difluorodithiopyruvic acid derivatives

Yuriy Grigorievich Shermolovich 1
Yuriy Grigorievich Shermolovich
, 
Vadim M Timoshenko 1
Vadim M Timoshenko
, 
Vitaliy Vladimirovich Listvan 1
Vitaliy Vladimirovich Listvan
, 
Leonid Nikolaevich Markovsky 1
Leonid Nikolaevich Markovsky
1 Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
10.1070/MC1998v008n06ABEH000971
Published 1998-12-16
Communication , Volume 8, Issue 6, 245-246
3
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Shermolovich Y. G. et al. Synthesis of difluorodithiopyruvic acid derivatives // Mendeleev Communications. 1998. Vol. 8. No. 6. pp. 245-246.
GOST all authors (up to 50) Copy
Shermolovich Y. G., Timoshenko V. M., Listvan V. V., Markovsky L. N. Synthesis of difluorodithiopyruvic acid derivatives // Mendeleev Communications. 1998. Vol. 8. No. 6. pp. 245-246.
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TY - JOUR
DO - 10.1070/MC1998v008n06ABEH000971
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n06ABEH000971
TI - Synthesis of difluorodithiopyruvic acid derivatives
T2 - Mendeleev Communications
AU - Shermolovich, Yuriy Grigorievich
AU - Timoshenko, Vadim M
AU - Listvan, Vitaliy Vladimirovich
AU - Markovsky, Leonid Nikolaevich
PY - 1998
DA - 1998/12/16
PB - Mendeleev Communications
SP - 245-246
IS - 6
VL - 8
ER -
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@article{1998_Shermolovich,
author = {Yuriy Grigorievich Shermolovich and Vadim M Timoshenko and Vitaliy Vladimirovich Listvan and Leonid Nikolaevich Markovsky},
title = {Synthesis of difluorodithiopyruvic acid derivatives},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n06ABEH000971},
number = {6},
pages = {245--246},
doi = {10.1070/MC1998v008n06ABEH000971}
}
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MLA Copy
Shermolovich, Yuriy Grigorievich, et al. “Synthesis of difluorodithiopyruvic acid derivatives.” Mendeleev Communications, vol. 8, no. 6, Dec. 1998, pp. 245-246. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n06ABEH000971.

Abstract

The reaction of cadmium sulfide with 1,1-dichloro-3,3-difluoro-2-oxo-1-propylthiopropane yields difluorodithiopyruvic propionate. This reacts with morpholine to give difluorodithiopyruvic morpholide; it also undergoes a cycloaddition reaction to the carbon–sulfur double bond with dimethylbutadiene to form 2-difluoroacetyl-4,5-dimethyl-2-propylthio-3H,6H-thiopyran.

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