Home / Publications / The first example of the catalytic activity of (μ-H)Os3(μ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group

The first example of the catalytic activity of (μ-H)Os3(μ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group

Victoriya Anatol'evna Ershova 1
Victoriya Anatol'evna Ershova
, 
Sergei Viktorovich Tkachev 1
Sergei Viktorovich Tkachev
, 
Anatoly Vasilyvich Golovin 1
Anatoly Vasilyvich Golovin
, 
Leonid Yakovlevich Al't 1
Leonid Yakovlevich Al't
10.1070/MC1998v008n06ABEH000962
Published 1998-12-16
Communication , Volume 8, Issue 6, 208-210
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Ershova V. A. et al. The first example of the catalytic activity of (μ-H)Os3(μ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group // Mendeleev Communications. 1998. Vol. 8. No. 6. pp. 208-210.
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Ershova V. A., Tkachev S. V., Golovin A. V., Al't L. Y. The first example of the catalytic activity of (μ-H)Os3(μ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group // Mendeleev Communications. 1998. Vol. 8. No. 6. pp. 208-210.
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TY - JOUR
DO - 10.1070/MC1998v008n06ABEH000962
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n06ABEH000962
TI - The first example of the catalytic activity of (μ-H)Os3(μ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group
T2 - Mendeleev Communications
AU - Ershova, Victoriya Anatol'evna
AU - Tkachev, Sergei Viktorovich
AU - Golovin, Anatoly Vasilyvich
AU - Al't, Leonid Yakovlevich
PY - 1998
DA - 1998/12/16
PB - Mendeleev Communications
SP - 208-210
IS - 6
VL - 8
ER -
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@article{1998_Ershova,
author = {Victoriya Anatol'evna Ershova and Sergei Viktorovich Tkachev and Anatoly Vasilyvich Golovin and Leonid Yakovlevich Al't},
title = {The first example of the catalytic activity of (μ-H)Os3(μ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n06ABEH000962},
number = {6},
pages = {208--210},
doi = {10.1070/MC1998v008n06ABEH000962}
}
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Ershova, Victoriya Anatol'evna, et al. “The first example of the catalytic activity of (μ-H)Os3(μ-OCNR1R2)(CO)10 clusters in the double bond migration reactions of allylic systems functionalised with an amido group.” Mendeleev Communications, vol. 8, no. 6, Dec. 1998, pp. 208-210. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n06ABEH000962.

Abstract

As exemplified by the isomerisation of N-allylacetamide in the presence of hydridocarbonyl complexes (μ-H)Os3(μ-OCNR1R2)(CO)10 (R1 = H, Alk; R2 = Alk), it has been demonstrated for the first time that they are effective catalysts for the [1,2]-double bond shift under mild conditions in allylic compounds functionalised with an amido group.

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