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Reaction of thioacetic acid with ethenyl- and ethynyl chlorides

Svetlana Grigorievna Dyachkova 1
Svetlana Grigorievna Dyachkova
, 
Elena A Beskrylaya 1
Elena A Beskrylaya
, 
Alexander Ivanovich Albanov 1
Alexander Ivanovich Albanov
, 
Lidia Mikhailovna Sinegovskaya 1
Lidia Mikhailovna Sinegovskaya
, 
Anastasia G Malkina 1
Anastasia G Malkina
, 
Terje A Skotheim 2
Terje A Skotheim
, 
Boris Aleksandrovich Trofimov 1
Boris Aleksandrovich Trofimov
10.1070/MC1998v008n05ABEH000992
Published 1998-09-10
Communication , Volume 8, Issue 5, 185-186
2
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Dyachkova S. G. et al. Reaction of thioacetic acid with ethenyl- and ethynyl chlorides // Mendeleev Communications. 1998. Vol. 8. No. 5. pp. 185-186.
GOST all authors (up to 50) Copy
Dyachkova S. G., Beskrylaya E. A., Albanov A. I., Sinegovskaya L. M., Malkina A. G., Skotheim T. A., Trofimov B. A. Reaction of thioacetic acid with ethenyl- and ethynyl chlorides // Mendeleev Communications. 1998. Vol. 8. No. 5. pp. 185-186.
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TY - JOUR
DO - 10.1070/MC1998v008n05ABEH000992
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000992
TI - Reaction of thioacetic acid with ethenyl- and ethynyl chlorides
T2 - Mendeleev Communications
AU - Dyachkova, Svetlana Grigorievna
AU - Beskrylaya, Elena A
AU - Albanov, Alexander Ivanovich
AU - Sinegovskaya, Lidia Mikhailovna
AU - Malkina, Anastasia G
AU - Skotheim, Terje A
AU - Trofimov, Boris Aleksandrovich
PY - 1998
DA - 1998/09/10
PB - Mendeleev Communications
SP - 185-186
IS - 5
VL - 8
ER -
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@article{1998_Dyachkova,
author = {Svetlana Grigorievna Dyachkova and Elena A Beskrylaya and Alexander Ivanovich Albanov and Lidia Mikhailovna Sinegovskaya and Anastasia G Malkina and Terje A Skotheim and Boris Aleksandrovich Trofimov},
title = {Reaction of thioacetic acid with ethenyl- and ethynyl chlorides},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000992},
number = {5},
pages = {185--186},
doi = {10.1070/MC1998v008n05ABEH000992}
}
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Dyachkova, Svetlana Grigorievna, et al. “Reaction of thioacetic acid with ethenyl- and ethynyl chlorides.” Mendeleev Communications, vol. 8, no. 5, Sep. 1998, pp. 185-186. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000992.

Abstract

Thioacetic acid (TAA) has been subjected to dichlorovinylation with trichloroethene (TCE) under free-radical conditions to form 1-acetylthio-2,2-dichloroethene 1 (yield 70%) which reacts with TAA at room temperature under phase-transfer catalysis conditions to afford a mixture of E- and Z-isomers of 1,2-bis(acetylthio)-2-chloroethene 2 (total yield 71%); ethylthio(chloro)ethyne with sodium thioacetate gives acetylthio(ethylthio)ethyne 3.

References

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