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The effect of pressure on the equilibrium in the Diels–Alder reaction between 9-chloroanthracene and tetracyanoethylene

Vladimir Dmitrievich Kiselev 1
Vladimir Dmitrievich Kiselev
, 
Elena Aleksandrovna Kashaeva 1
Elena Aleksandrovna Kashaeva
, 
Aleksandr Ivanovich Konovalov 1
Aleksandr Ivanovich Konovalov
10.1070/MC1998v008n05ABEH000985
Published 1998-09-10
Communication , Volume 8, Issue 5, 192-193
3
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Kiselev V. D., Kashaeva E. A., Konovalov A. I. The effect of pressure on the equilibrium in the Diels–Alder reaction between 9-chloroanthracene and tetracyanoethylene // Mendeleev Communications. 1998. Vol. 8. No. 5. pp. 192-193.
GOST all authors (up to 50) Copy
Kiselev V. D., Kashaeva E. A., Konovalov A. I. The effect of pressure on the equilibrium in the Diels–Alder reaction between 9-chloroanthracene and tetracyanoethylene // Mendeleev Communications. 1998. Vol. 8. No. 5. pp. 192-193.
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TY - JOUR
DO - 10.1070/MC1998v008n05ABEH000985
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000985
TI - The effect of pressure on the equilibrium in the Diels–Alder reaction between 9-chloroanthracene and tetracyanoethylene
T2 - Mendeleev Communications
AU - Kiselev, Vladimir Dmitrievich
AU - Kashaeva, Elena Aleksandrovna
AU - Konovalov, Aleksandr Ivanovich
PY - 1998
DA - 1998/09/10
PB - Mendeleev Communications
SP - 192-193
IS - 5
VL - 8
ER -
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@article{1998_Kiselev,
author = {Vladimir Dmitrievich Kiselev and Elena Aleksandrovna Kashaeva and Aleksandr Ivanovich Konovalov},
title = {The effect of pressure on the equilibrium in the Diels–Alder reaction between 9-chloroanthracene and tetracyanoethylene},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000985},
number = {5},
pages = {192--193},
doi = {10.1070/MC1998v008n05ABEH000985}
}
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Kiselev, Vladimir Dmitrievich, et al. “The effect of pressure on the equilibrium in the Diels–Alder reaction between 9-chloroanthracene and tetracyanoethylene.” Mendeleev Communications, vol. 8, no. 5, Sep. 1998, pp. 192-193. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000985.

Abstract

Equilibrium constants for the Diels–Alder reaction of 9-chloroanthracene with tetracyanoethylene have been determined in the pressure range 0–970 kg cm–2 in 1,2-dichloroethane at 298 K and the value of the reaction volume (–20.6±1.5 cm3 mol–1) has been compared with the difference in partial molar volume of the dienophile (107.8±0.2), diene (170.7±0.5) and adduct (255.5±1.5 cm3 mol–1).

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