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Kinetic mechanism and chemical oscillations in the branching chain decomposition of nitrogen trichloride

Nikolai Mihailovich Rubtsov 1
Nikolai Mihailovich Rubtsov
10.1070/MC1998v008n05ABEH000948
Published 1998-09-10
Communication , Volume 8, Issue 5, 173-176
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Rubtsov N. M. Kinetic mechanism and chemical oscillations in the branching chain decomposition of nitrogen trichloride // Mendeleev Communications. 1998. Vol. 8. No. 5. pp. 173-176.
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Rubtsov N. M. Kinetic mechanism and chemical oscillations in the branching chain decomposition of nitrogen trichloride // Mendeleev Communications. 1998. Vol. 8. No. 5. pp. 173-176.
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TY - JOUR
DO - 10.1070/MC1998v008n05ABEH000948
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000948
TI - Kinetic mechanism and chemical oscillations in the branching chain decomposition of nitrogen trichloride
T2 - Mendeleev Communications
AU - Rubtsov, Nikolai Mihailovich
PY - 1998
DA - 1998/09/10
PB - Mendeleev Communications
SP - 173-176
IS - 5
VL - 8
ER -
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@article{1998_Rubtsov,
author = {Nikolai Mihailovich Rubtsov},
title = {Kinetic mechanism and chemical oscillations in the branching chain decomposition of nitrogen trichloride},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000948},
number = {5},
pages = {173--176},
doi = {10.1070/MC1998v008n05ABEH000948}
}
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Rubtsov, Nikolai Mihailovich. “Kinetic mechanism and chemical oscillations in the branching chain decomposition of nitrogen trichloride.” Mendeleev Communications, vol. 8, no. 5, Sep. 1998, pp. 173-176. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000948.

Abstract

On the basis of numerical simulation of the branching chain process of the decomposition of nitrogen trichloride it has been shown that suitable conditions for providing oscillating regimes are the following: (a) inclusion of adsorption–desorption of NCl3 on the reactor walls; (b) inclusion of nonlinear chain branching and breaking reactions.

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