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Formation of singlet oxygen in the system tris(bipyridine)ruthenium(II)–dimethyldioxirane

Dmitri Valer'evich Kazakov 1
Dmitri Valer'evich Kazakov
, 
Aleksandr Iosifovich Voloshin 1
Aleksandr Iosifovich Voloshin
, 
Valerii Vladimirovich Shereshovets 1
Valerii Vladimirovich Shereshovets
, 
Valerii Nikolaevich Yakovlev 1
Valerii Nikolaevich Yakovlev
, 
Valeri Petrovich Kazakov 1
Valeri Petrovich Kazakov
10.1070/MC1998v008n05ABEH000936
Published 1998-09-10
Communication , Volume 8, Issue 5, 169-170
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Kazakov D. V. et al. Formation of singlet oxygen in the system tris(bipyridine)ruthenium(II)–dimethyldioxirane // Mendeleev Communications. 1998. Vol. 8. No. 5. pp. 169-170.
GOST all authors (up to 50) Copy
Kazakov D. V., Voloshin A. I., Shereshovets V. V., Yakovlev V. N., Kazakov V. P. Formation of singlet oxygen in the system tris(bipyridine)ruthenium(II)–dimethyldioxirane // Mendeleev Communications. 1998. Vol. 8. No. 5. pp. 169-170.
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TY - JOUR
DO - 10.1070/MC1998v008n05ABEH000936
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000936
TI - Formation of singlet oxygen in the system tris(bipyridine)ruthenium(II)–dimethyldioxirane
T2 - Mendeleev Communications
AU - Kazakov, Dmitri Valer'evich
AU - Voloshin, Aleksandr Iosifovich
AU - Shereshovets, Valerii Vladimirovich
AU - Yakovlev, Valerii Nikolaevich
AU - Kazakov, Valeri Petrovich
PY - 1998
DA - 1998/09/10
PB - Mendeleev Communications
SP - 169-170
IS - 5
VL - 8
ER -
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@article{1998_Kazakov,
author = {Dmitri Valer'evich Kazakov and Aleksandr Iosifovich Voloshin and Valerii Vladimirovich Shereshovets and Valerii Nikolaevich Yakovlev and Valeri Petrovich Kazakov},
title = {Formation of singlet oxygen in the system tris(bipyridine)ruthenium(II)–dimethyldioxirane},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000936},
number = {5},
pages = {169--170},
doi = {10.1070/MC1998v008n05ABEH000936}
}
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Kazakov, Dmitri Valer'evich, et al. “Formation of singlet oxygen in the system tris(bipyridine)ruthenium(II)–dimethyldioxirane.” Mendeleev Communications, vol. 8, no. 5, Sep. 1998, pp. 169-170. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n05ABEH000936.

Abstract

Decomposition of dimethyldioxirane in the presence of tris(bipyridine)ruthenium(II) complex (RuII) is accompanied by chemiluminescence (CL) in the infrared spectrum region (1270 nm) due to the formation of singlet oxygen; reaction between RuIII and superoxide ion, which is formed in this process via a sequence of electron-transfer reactions, is assumed to be a CL step.

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