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Low-temperature radiation polymerization of cyanogen bromide

Galina Anatol'evna Kichigina 1
Galina Anatol'evna Kichigina
, 
Pavel Stanislavovich Mozhaev 1
Pavel Stanislavovich Mozhaev
,  , 
Igor Mstislavovich Barkalov 1
Igor Mstislavovich Barkalov
10.1070/MC1998v008n04ABEH000939
Published 1998-09-10
Communication , Volume 8, Issue 4, 159-160
2
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Kichigina G. A. et al. Low-temperature radiation polymerization of cyanogen bromide // Mendeleev Communications. 1998. Vol. 8. No. 4. pp. 159-160.
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Kichigina G. A., Mozhaev P. S., Kiryukhin D. P., Barkalov I. M. Low-temperature radiation polymerization of cyanogen bromide // Mendeleev Communications. 1998. Vol. 8. No. 4. pp. 159-160.
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TY - JOUR
DO - 10.1070/MC1998v008n04ABEH000939
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n04ABEH000939
TI - Low-temperature radiation polymerization of cyanogen bromide
T2 - Mendeleev Communications
AU - Kichigina, Galina Anatol'evna
AU - Mozhaev, Pavel Stanislavovich
AU - Kiryukhin, Dmitrii Pavlovich
AU - Barkalov, Igor Mstislavovich
PY - 1998
DA - 1998/09/10
PB - Mendeleev Communications
SP - 159-160
IS - 4
VL - 8
ER -
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@article{1998_Kichigina,
author = {Galina Anatol'evna Kichigina and Pavel Stanislavovich Mozhaev and Dmitrii Pavlovich Kiryukhin and Igor Mstislavovich Barkalov},
title = {Low-temperature radiation polymerization of cyanogen bromide},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n04ABEH000939},
number = {4},
pages = {159--160},
doi = {10.1070/MC1998v008n04ABEH000939}
}
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Kichigina, Galina Anatol'evna, et al. “Low-temperature radiation polymerization of cyanogen bromide.” Mendeleev Communications, vol. 8, no. 4, Sep. 1998, pp. 159-160. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n04ABEH000939.

Abstract

The absence in crystalline cyanogen bromide of intermolecular chains with strong N…H hydrogen bonds typical of the HCN crystal causes a difference in cryopolymerization in these monomers. Heat release is observed during defrosting of radiolysed cyanogen bromide, connected with its polymerization at 220–230 K. There is another heat release due to polymerization of cyanogen bromide in the melting region. The dependence of the yield of the polymer forming in the melting regions on the irradiation dose has an extreme character. We assume that the suppression of the polymerization of cyanogen bromide in the melting region is connected with progressive destruction of the matrix structure during irradiation.

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