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Mechanism of the inhibiting action of electrolytes on the micellar effect in alkaline hydrolysis of p-nitrophenyl ethyl chloromethylphosphonate

Lucia Yarullovna Zakharova 1
Lucia Yarullovna Zakharova
, 
Lyudmila Andreevna Kudryavtseva 1
Lyudmila Andreevna Kudryavtseva
, 
Aleksandr Ivanovich Konovalov 2
Aleksandr Ivanovich Konovalov
10.1070/MC1998v008n04ABEH000914
Published 1998-09-10
Communication , Volume 8, Issue 4, 163-165
12
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Zakharova L. Y., Kudryavtseva L. A., Konovalov A. I. Mechanism of the inhibiting action of electrolytes on the micellar effect in alkaline hydrolysis of p-nitrophenyl ethyl chloromethylphosphonate // Mendeleev Communications. 1998. Vol. 8. No. 4. pp. 163-165.
GOST all authors (up to 50) Copy
Zakharova L. Y., Kudryavtseva L. A., Konovalov A. I. Mechanism of the inhibiting action of electrolytes on the micellar effect in alkaline hydrolysis of p-nitrophenyl ethyl chloromethylphosphonate // Mendeleev Communications. 1998. Vol. 8. No. 4. pp. 163-165.
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TY - JOUR
DO - 10.1070/MC1998v008n04ABEH000914
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n04ABEH000914
TI - Mechanism of the inhibiting action of electrolytes on the micellar effect in alkaline hydrolysis of p-nitrophenyl ethyl chloromethylphosphonate
T2 - Mendeleev Communications
AU - Zakharova, Lucia Yarullovna
AU - Kudryavtseva, Lyudmila Andreevna
AU - Konovalov, Aleksandr Ivanovich
PY - 1998
DA - 1998/09/10
PB - Mendeleev Communications
SP - 163-165
IS - 4
VL - 8
ER -
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@article{1998_Zakharova,
author = {Lucia Yarullovna Zakharova and Lyudmila Andreevna Kudryavtseva and Aleksandr Ivanovich Konovalov},
title = {Mechanism of the inhibiting action of electrolytes on the micellar effect in alkaline hydrolysis of p-nitrophenyl ethyl chloromethylphosphonate},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Sep},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n04ABEH000914},
number = {4},
pages = {163--165},
doi = {10.1070/MC1998v008n04ABEH000914}
}
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Zakharova, Lucia Yarullovna, et al. “Mechanism of the inhibiting action of electrolytes on the micellar effect in alkaline hydrolysis of p-nitrophenyl ethyl chloromethylphosphonate.” Mendeleev Communications, vol. 8, no. 4, Sep. 1998, pp. 163-165. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n04ABEH000914.

Abstract

The influence of KCl, KBr and sodium salicylate (NaSal) on the micellar effect of cetylpyridinium bromide in the alkaline hydrolysis of p-nitrophenyl ethyl chloromethylphosphonate has been studied and the effects of electrolytes on the rate constant and surface potential compared; based on the data obtained, it can be concluded that the reaction inhibition is determined both by a change in the structure and properties of the micellar aggregates and by a decrease in the concentration of the nucleophile in the micelles due to a decrease in the surface potential.

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