Home / Publications / Chemiluminescence of Pr3+ in the visible region from the 3P1, 3P0, 1D2 levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by β-diketonates Pr(fod)3 and Pr(dpm)3. An unusual route for activator chemiexcitation

Chemiluminescence of Pr3+ in the visible region from the 3P1, 3P0, 1D2 levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by β-diketonates Pr(fod)3 and Pr(dpm)3. An unusual route for activator chemiexcitation

Valeri Petrovich Kazakov 1
Valeri Petrovich Kazakov
, 
Aleksandr Iosifovich Voloshin 1
Aleksandr Iosifovich Voloshin
, 
Nail' Malikovich Shavaleev 1
Nail' Malikovich Shavaleev
10.1070/MC1998v008n03ABEH000940
Published 1998-07-06
Communication , Volume 8, Issue 3, 110-112
6
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Kazakov V. P., Voloshin A. I., Shavaleev N. M. Chemiluminescence of Pr3+ in the visible region from the 3P1, 3P0, 1D2 levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by β-diketonates Pr(fod)3 and Pr(dpm)3. An unusual route for activator chemiexcitation // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 110-112.
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Kazakov V. P., Voloshin A. I., Shavaleev N. M. Chemiluminescence of Pr3+ in the visible region from the 3P1, 3P0, 1D2 levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by β-diketonates Pr(fod)3 and Pr(dpm)3. An unusual route for activator chemiexcitation // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 110-112.
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TY - JOUR
DO - 10.1070/MC1998v008n03ABEH000940
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000940
TI - Chemiluminescence of Pr3+ in the visible region from the 3P1, 3P0, 1D2 levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by β-diketonates Pr(fod)3 and Pr(dpm)3. An unusual route for activator chemiexcitation
T2 - Mendeleev Communications
AU - Kazakov, Valeri Petrovich
AU - Voloshin, Aleksandr Iosifovich
AU - Shavaleev, Nail' Malikovich
PY - 1998
DA - 1998/07/06
PB - Mendeleev Communications
SP - 110-112
IS - 3
VL - 8
ER -
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@article{1998_Kazakov,
author = {Valeri Petrovich Kazakov and Aleksandr Iosifovich Voloshin and Nail' Malikovich Shavaleev},
title = {Chemiluminescence of Pr3+ in the visible region from the 3P1, 3P0, 1D2 levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by β-diketonates Pr(fod)3 and Pr(dpm)3. An unusual route for activator chemiexcitation},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000940},
number = {3},
pages = {110--112},
doi = {10.1070/MC1998v008n03ABEH000940}
}
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Kazakov, Valeri Petrovich, et al. “Chemiluminescence of Pr3+ in the visible region from the 3P1, 3P0, 1D2 levels upon decomposition of adamantylideneadamantane-1,2-dioxetane catalysed by β-diketonates Pr(fod)3 and Pr(dpm)3. An unusual route for activator chemiexcitation.” Mendeleev Communications, vol. 8, no. 3, Jul. 1998, pp. 110-112. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000940.

Abstract

Chemiluminescence of Pr3+ is observed upon decomposition of adamantylideneadamantane-1,2-dioxetane (AAD) catalysed by β-diketonates Pr(L)3 (L = fod or dpm), the excitation of Pr3+ occurring through intracomplex energy transfer from the excited adamantanone formed upon decomposition of AAD in the complex Pr(L)3·AAD.

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