Home / Publications / The determination of the molecular structure of 2-fluoro-3,5-di-tert-butyl-1,3,2-oxazaphospholene by means of electron diffraction and ab initio calculations

The determination of the molecular structure of 2-fluoro-3,5-di-tert-butyl-1,3,2-oxazaphospholene by means of electron diffraction and ab initio calculations

Victor Anatol'evich Naumov 1
Victor Anatol'evich Naumov
, 
Marwan Dakkouri 2
Marwan Dakkouri
, 
Rida Nazipovna Ziatdinova 1
Rida Nazipovna Ziatdinova
, 
Heinz Oberhammer 3
Heinz Oberhammer
10.1070/MC1998v008n03ABEH000930
Published 1998-07-06
Communication , Volume 8, Issue 3, 89-90
3
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Naumov V. A. et al. The determination of the molecular structure of 2-fluoro-3,5-di-tert-butyl-1,3,2-oxazaphospholene by means of electron diffraction and ab initio calculations // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 89-90.
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Naumov V. A., Dakkouri M., Ziatdinova R. N., Oberhammer H. The determination of the molecular structure of 2-fluoro-3,5-di-tert-butyl-1,3,2-oxazaphospholene by means of electron diffraction and ab initio calculations // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 89-90.
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TY - JOUR
DO - 10.1070/MC1998v008n03ABEH000930
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000930
TI - The determination of the molecular structure of 2-fluoro-3,5-di-tert-butyl-1,3,2-oxazaphospholene by means of electron diffraction and ab initio calculations
T2 - Mendeleev Communications
AU - Naumov, Victor Anatol'evich
AU - Dakkouri, Marwan
AU - Ziatdinova, Rida Nazipovna
AU - Oberhammer, Heinz
PY - 1998
DA - 1998/07/06
PB - Mendeleev Communications
SP - 89-90
IS - 3
VL - 8
ER -
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@article{1998_Naumov,
author = {Victor Anatol'evich Naumov and Marwan Dakkouri and Rida Nazipovna Ziatdinova and Heinz Oberhammer},
title = {The determination of the molecular structure of 2-fluoro-3,5-di-tert-butyl-1,3,2-oxazaphospholene by means of electron diffraction and ab initio calculations},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000930},
number = {3},
pages = {89--90},
doi = {10.1070/MC1998v008n03ABEH000930}
}
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Naumov, Victor Anatol'evich, et al. “The determination of the molecular structure of 2-fluoro-3,5-di-tert-butyl-1,3,2-oxazaphospholene by means of electron diffraction and ab initio calculations.” Mendeleev Communications, vol. 8, no. 3, Jul. 1998, pp. 89-90. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000930.

Abstract

The molecular structure of gaseous 2-fluoro-3,5-di-tert-butyl-1,3,2-oxazaphospholene has been determined by electron diffraction and ab initio calculations. The structural analysis has shown that the diheterophospholene ring possesses a P-envelope conformation with axial orientation of the P–F bond which is very long, 1.641(11) Å.

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