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Sterically controlled population of the 1,2-cis-form of 1,2-dimethyl-3-tert-butyldiaziridine

Remir Grigorevich Kostyanovsky 1
Remir Grigorevich Kostyanovsky
, 
Gennady Vital'evich Shustov 1
Gennady Vital'evich Shustov
, 
Vladimir V Starovoitov 1
Vladimir V Starovoitov
, 
Ivan Ivanovich Chervin 1
Ivan Ivanovich Chervin
10.1070/MC1998v008n03ABEH000916
Published 1998-07-06
Communication , Volume 8, Issue 3, 113-116
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Kostyanovsky R. G. et al. Sterically controlled population of the 1,2-cis-form of 1,2-dimethyl-3-tert-butyldiaziridine // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 113-116.
GOST all authors (up to 50) Copy
Kostyanovsky R. G., Shustov G. V., Starovoitov V. V., Chervin I. I. Sterically controlled population of the 1,2-cis-form of 1,2-dimethyl-3-tert-butyldiaziridine // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 113-116.
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TY - JOUR
DO - 10.1070/MC1998v008n03ABEH000916
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000916
TI - Sterically controlled population of the 1,2-cis-form of 1,2-dimethyl-3-tert-butyldiaziridine
T2 - Mendeleev Communications
AU - Kostyanovsky, Remir Grigorevich
AU - Shustov, Gennady Vital'evich
AU - Starovoitov, Vladimir V
AU - Chervin, Ivan Ivanovich
PY - 1998
DA - 1998/07/06
PB - Mendeleev Communications
SP - 113-116
IS - 3
VL - 8
ER -
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@article{1998_Kostyanovsky,
author = {Remir Grigorevich Kostyanovsky and Gennady Vital'evich Shustov and Vladimir V Starovoitov and Ivan Ivanovich Chervin},
title = {Sterically controlled population of the 1,2-cis-form of 1,2-dimethyl-3-tert-butyldiaziridine},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000916},
number = {3},
pages = {113--116},
doi = {10.1070/MC1998v008n03ABEH000916}
}
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Kostyanovsky, Remir Grigorevich, et al. “Sterically controlled population of the 1,2-cis-form of 1,2-dimethyl-3-tert-butyldiaziridine.” Mendeleev Communications, vol. 8, no. 3, Jul. 1998, pp. 113-116. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000916.

Abstract

1,2-Dimethyl-3-R-diaziridine (R = But) has been synthesized for the first time; as revealed by NMR the population of its 1,2-cis-form was shown to increase in polar solvents [1,2-cis/1,2-trans = 2 (D2O), 0.5 (CDCl3), 0.03 (C6D6); for 1,2-trans →1,2-cis in C6D6 at 32 °C ΔG# = 25 kcal mol−1] whereas solely the 1,2-trans-form was detected in diaziridines when R = Me, Et, Pri, Ph.

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