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Unusual heterocyclisation in the transformation of 6-halomethylsulfonyl-substituted bicyclo[3.1.1]heptane under Ramberg–Bäcklund reaction conditions

Viktor Alekseevich Vasin 1
Viktor Alekseevich Vasin
, 
Ella Viktorovna Romanova 1
Ella Viktorovna Romanova
, 
Sergei Gennadievich Kostryukov 1
Sergei Gennadievich Kostryukov
, 
Vyacheslav Vasil'evich Razin 2
Vyacheslav Vasil'evich Razin
10.1070/MC1998v008n03ABEH000913
Published 1998-07-06
Communication , Volume 8, Issue 3, 122-125
7
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Vasin V. A. et al. Unusual heterocyclisation in the transformation of 6-halomethylsulfonyl-substituted bicyclo[3.1.1]heptane under Ramberg–Bäcklund reaction conditions // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 122-125.
GOST all authors (up to 50) Copy
Vasin V. A., Romanova E. V., Kostryukov S. G., Razin V. V. Unusual heterocyclisation in the transformation of 6-halomethylsulfonyl-substituted bicyclo[3.1.1]heptane under Ramberg–Bäcklund reaction conditions // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 122-125.
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TY - JOUR
DO - 10.1070/MC1998v008n03ABEH000913
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000913
TI - Unusual heterocyclisation in the transformation of 6-halomethylsulfonyl-substituted bicyclo[3.1.1]heptane under Ramberg–Bäcklund reaction conditions
T2 - Mendeleev Communications
AU - Vasin, Viktor Alekseevich
AU - Romanova, Ella Viktorovna
AU - Kostryukov, Sergei Gennadievich
AU - Razin, Vyacheslav Vasil'evich
PY - 1998
DA - 1998/07/06
PB - Mendeleev Communications
SP - 122-125
IS - 3
VL - 8
ER -
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@article{1998_Vasin,
author = {Viktor Alekseevich Vasin and Ella Viktorovna Romanova and Sergei Gennadievich Kostryukov and Vyacheslav Vasil'evich Razin},
title = {Unusual heterocyclisation in the transformation of 6-halomethylsulfonyl-substituted bicyclo[3.1.1]heptane under Ramberg–Bäcklund reaction conditions},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000913},
number = {3},
pages = {122--125},
doi = {10.1070/MC1998v008n03ABEH000913}
}
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Vasin, Viktor Alekseevich, et al. “Unusual heterocyclisation in the transformation of 6-halomethylsulfonyl-substituted bicyclo[3.1.1]heptane under Ramberg–Bäcklund reaction conditions.” Mendeleev Communications, vol. 8, no. 3, Jul. 1998, pp. 122-125. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000913.

Abstract

Boiling of exo-6-bromo-syn-7-bromo(chloro)methylsulfonyl-endo-6-phenylbicyclo[3.1.1]heptane in water–dioxane solutions of NaOH results in anti-6-hydroxy-7-methylene-syn-6-phenylbicyclo[3.1.1]heptane according to the Ramberg–Bäcklund reaction; in addition, a product of unusual heterocyclisation is formed, namely, 3-oxa-2-phenyl-5-thiatricyclo[4.4.0.02,7]decane S,S-dioxide.

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