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Identification of matrix-isolated methoxyl radicals by recording EPR spectra under photolysis

Irina Vasil'evna Malakhova 1
Irina Vasil'evna Malakhova
, 
Vladimir Konstantinovich Ermolaev 1
Vladimir Konstantinovich Ermolaev
10.1070/MC1998v008n03ABEH000911
Published 1998-07-06
Communication , Volume 8, Issue 3, 83-84
2
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Malakhova I. V., Ermolaev V. K. Identification of matrix-isolated methoxyl radicals by recording EPR spectra under photolysis // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 83-84.
GOST all authors (up to 50) Copy
Malakhova I. V., Ermolaev V. K. Identification of matrix-isolated methoxyl radicals by recording EPR spectra under photolysis // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 83-84.
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TY - JOUR
DO - 10.1070/MC1998v008n03ABEH000911
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000911
TI - Identification of matrix-isolated methoxyl radicals by recording EPR spectra under photolysis
T2 - Mendeleev Communications
AU - Malakhova, Irina Vasil'evna
AU - Ermolaev, Vladimir Konstantinovich
PY - 1998
DA - 1998/07/06
PB - Mendeleev Communications
SP - 83-84
IS - 3
VL - 8
ER -
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@article{1998_Malakhova,
author = {Irina Vasil'evna Malakhova and Vladimir Konstantinovich Ermolaev},
title = {Identification of matrix-isolated methoxyl radicals by recording EPR spectra under photolysis},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000911},
number = {3},
pages = {83--84},
doi = {10.1070/MC1998v008n03ABEH000911}
}
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Malakhova, Irina Vasil'evna, and Vladimir Konstantinovich Ermolaev. “Identification of matrix-isolated methoxyl radicals by recording EPR spectra under photolysis.” Mendeleev Communications, vol. 8, no. 3, Jul. 1998, pp. 83-84. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000911.

Abstract

For the first time gas phase radicals have been observed, using the matrix isolation method, during methanol oxidation on a Pt/SiO2 catalyst. A method of identifying the radicals generated is suggested, which utilises the differing resistance of MeO· and MeO·2 radicals to photolysis using the full light of a high pressure mercury lamp.

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