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The effect of the structure of Cu–Ti oxide systems obtained by sol–gel synthesis on the nature of catalytic centres and catalytic activity in low-temperature CO oxidation

Elena Alekseevna Trusova 1
Elena Alekseevna Trusova
, 
Mark Veniaminivich Tsodikov 1
Mark Veniaminivich Tsodikov
, 
Evgenii Viktorovich Slivinskii 1
Evgenii Viktorovich Slivinskii
, 
Gustavo G Hernandes 1
Gustavo G Hernandes
, 
Olga Vladimirovna Bukhtenko 1
Olga Vladimirovna Bukhtenko
, 
Tatiana N Zhdanova 1
Tatiana N Zhdanova
, 
Dmitrii Ivanovich Kochubey 2
Dmitrii Ivanovich Kochubey
, 
Jose A Navio 3
Jose A Navio
10.1070/MC1998v008n03ABEH000663
Published 1998-07-06
Communication , Volume 8, Issue 3, 102-104
11
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Trusova E. A. et al. The effect of the structure of Cu–Ti oxide systems obtained by sol–gel synthesis on the nature of catalytic centres and catalytic activity in low-temperature CO oxidation // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 102-104.
GOST all authors (up to 50) Copy
Trusova E. A., Tsodikov M. V., Slivinskii E. V., Hernandes G. G., Bukhtenko O. V., Zhdanova T. N., Kochubey D. I., Navio J. A. The effect of the structure of Cu–Ti oxide systems obtained by sol–gel synthesis on the nature of catalytic centres and catalytic activity in low-temperature CO oxidation // Mendeleev Communications. 1998. Vol. 8. No. 3. pp. 102-104.
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TY - JOUR
DO - 10.1070/MC1998v008n03ABEH000663
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000663
TI - The effect of the structure of Cu–Ti oxide systems obtained by sol–gel synthesis on the nature of catalytic centres and catalytic activity in low-temperature CO oxidation
T2 - Mendeleev Communications
AU - Trusova, Elena Alekseevna
AU - Tsodikov, Mark Veniaminivich
AU - Slivinskii, Evgenii Viktorovich
AU - Hernandes, Gustavo G
AU - Bukhtenko, Olga Vladimirovna
AU - Zhdanova, Tatiana N
AU - Kochubey, Dmitrii Ivanovich
AU - Navio, Jose A
PY - 1998
DA - 1998/07/06
PB - Mendeleev Communications
SP - 102-104
IS - 3
VL - 8
ER -
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@article{1998_Trusova,
author = {Elena Alekseevna Trusova and Mark Veniaminivich Tsodikov and Evgenii Viktorovich Slivinskii and Gustavo G Hernandes and Olga Vladimirovna Bukhtenko and Tatiana N Zhdanova and Dmitrii Ivanovich Kochubey and Jose A Navio},
title = {The effect of the structure of Cu–Ti oxide systems obtained by sol–gel synthesis on the nature of catalytic centres and catalytic activity in low-temperature CO oxidation},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Jul},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000663},
number = {3},
pages = {102--104},
doi = {10.1070/MC1998v008n03ABEH000663}
}
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Trusova, Elena Alekseevna, et al. “The effect of the structure of Cu–Ti oxide systems obtained by sol–gel synthesis on the nature of catalytic centres and catalytic activity in low-temperature CO oxidation.” Mendeleev Communications, vol. 8, no. 3, Jul. 1998, pp. 102-104. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n03ABEH000663.

Abstract

It has been shown by X-ray diffraction analysis, EXAFS and XPS methods and in experiments on the low-temperature oxidation of CO that two types of catalytic oxidation centres are formed during sol–gel synthesis of single-phase Cu–Ti oxide systems (0.5–5.0 mass% Cu) based on anatase: the first type involves Cu+ ions in the [111] crystal planes, while the second type involves Cu2+ ions, which isomorphically substitute titanium ions in the [100] planes of TiO2

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