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Reaction of glycidol with dichloroethers: cyclic and acyclic ortho ester formation

Alexander Alexandrovich Bredikhin 1
Alexander Alexandrovich Bredikhin
, 
Sergey N Lazarev 1
Sergey N Lazarev
10.1070/MC1998v008n02ABEH000919
Published 1998-04-28
Communication , Volume 8, Issue 2, 81-82
3
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Bredikhin A. A., Lazarev S. N. Reaction of glycidol with dichloroethers: cyclic and acyclic ortho ester formation // Mendeleev Communications. 1998. Vol. 8. No. 2. pp. 81-82.
GOST all authors (up to 50) Copy
Bredikhin A. A., Lazarev S. N. Reaction of glycidol with dichloroethers: cyclic and acyclic ortho ester formation // Mendeleev Communications. 1998. Vol. 8. No. 2. pp. 81-82.
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TY - JOUR
DO - 10.1070/MC1998v008n02ABEH000919
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n02ABEH000919
TI - Reaction of glycidol with dichloroethers: cyclic and acyclic ortho ester formation
T2 - Mendeleev Communications
AU - Bredikhin, Alexander Alexandrovich
AU - Lazarev, Sergey N
PY - 1998
DA - 1998/04/28
PB - Mendeleev Communications
SP - 81-82
IS - 2
VL - 8
ER -
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@article{1998_Bredikhin,
author = {Alexander Alexandrovich Bredikhin and Sergey N Lazarev},
title = {Reaction of glycidol with dichloroethers: cyclic and acyclic ortho ester formation},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n02ABEH000919},
number = {2},
pages = {81--82},
doi = {10.1070/MC1998v008n02ABEH000919}
}
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Bredikhin, Alexander Alexandrovich, and Sergey N Lazarev. “Reaction of glycidol with dichloroethers: cyclic and acyclic ortho ester formation.” Mendeleev Communications, vol. 8, no. 2, Apr. 1998, pp. 81-82. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n02ABEH000919.

Abstract

The interaction of stoichiometric quantities of glycidol with alkyl dichloromethyl ethers in the presence of 2 equiv. of NEt3 in diethyl ether leads to formation of diglycidyloxy alkoxy methanes whereas the same reaction involving equimolar quantities of the reagents in benzene in the presence of 1 equiv. of NEt3 leads to formation of 4-chloromethyl-2-alkoxy-1,3-dioxolanes.

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