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One-step synthesis of N-sulfonylazepines from sulfonylamides and benzene in the presence of XeF2

Sergey V Kovalenko 1
Sergey V Kovalenko
,  , 
Nikolai Serafimovich Zefirov 2
Nikolai Serafimovich Zefirov
, 
Peter J Stang 3
Peter J Stang
10.1070/MC1998v008n02ABEH000849
Published 1998-04-28
Communication , Volume 8, Issue 2, 68-68
6
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Kovalenko S. V. et al. One-step synthesis of N-sulfonylazepines from sulfonylamides and benzene in the presence of XeF2 // Mendeleev Communications. 1998. Vol. 8. No. 2. pp. 68-68.
GOST all authors (up to 50) Copy
Kovalenko S. V., Brel V. K., Zefirov N. S., Stang P. J. One-step synthesis of N-sulfonylazepines from sulfonylamides and benzene in the presence of XeF2 // Mendeleev Communications. 1998. Vol. 8. No. 2. pp. 68-68.
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TY - JOUR
DO - 10.1070/MC1998v008n02ABEH000849
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n02ABEH000849
TI - One-step synthesis of N-sulfonylazepines from sulfonylamides and benzene in the presence of XeF2
T2 - Mendeleev Communications
AU - Kovalenko, Sergey V
AU - Brel, Valery Kuzmich
AU - Zefirov, Nikolai Serafimovich
AU - Stang, Peter J
PY - 1998
DA - 1998/04/28
PB - Mendeleev Communications
SP - 68-68
IS - 2
VL - 8
ER -
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@article{1998_Kovalenko,
author = {Sergey V Kovalenko and Valery Kuzmich Brel and Nikolai Serafimovich Zefirov and Peter J Stang},
title = {One-step synthesis of N-sulfonylazepines from sulfonylamides and benzene in the presence of XeF2},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n02ABEH000849},
number = {2},
pages = {68--68},
doi = {10.1070/MC1998v008n02ABEH000849}
}
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Kovalenko, Sergey V., et al. “One-step synthesis of N-sulfonylazepines from sulfonylamides and benzene in the presence of XeF2.” Mendeleev Communications, vol. 8, no. 2, Apr. 1998, pp. 68-68. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n02ABEH000849.

Abstract

Reaction of benzene and sulfonylnitrene, generated in situ from sulfonamide tetrabutylammonium salts and xenon difluoride, gives N-sulfonylazepines.

References

1.
10.1070/MC1998v008n02ABEH000849_bib1
Bartlett
Proc. Chem. Soc., 1962
2.
10.1070/MC1998v008n02ABEH000849_bib2
New Fluorinating Agents in Organic Synthesis, 1989
3.
10.1070/MC1998v008n02ABEH000849_bib3
Tius
1995
4.
Reactions of Organic Compounds with Xenon Fluorides
Filler R.
Israel Journal of Chemistry, 1978
6.
10.1070/MC1998v008n02ABEH000849_bib5_2
Brel
Tetrahedron Lett., 1990
7.
1,.omega.-Perfluoroalkylation of aromatics via bis-decarboxylation of perfluorodicarboxylic acids with xenon difluoride
Brel V.K., Uvarov V.I., Zefirov N.S., Stang P.J., Caple R.
Journal of Organic Chemistry, 1993
8.
Synthesis of bridgehead fluorides by fluorodeiodination
Della E.W., Head N.J.
Journal of Organic Chemistry, 1992
11.
Phenyliodine(III) Sulfate as a New Reagent for Synthesis of Diaryliodonium Salts
Kasumov T.M., Brel V.K., Kos¿min A.S., Zefirov N.S.
Synthesis, 1995
13.
New one-pot method for the stereoselective synthesis of (E)-[β-(trifluoromethylsulfonyloxy)-alkenyl](Aryl) iodonium triflates
Kasumov T.M., Pirguliyev N.S., Brel V.K., Grishin Y.K., Zefirov N.S., Stang P.J.
Tetrahedron, 1997
14.
Unsaturated heterocyclic systems. LII. General synthetic entry to derivatives of 1H-azepine
Paquette L.A., Kuhla D.E., Barrett J.H., Haluska R.J.
Journal of Organic Chemistry, 1969