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Lipase-mediated stereodivergent synthesis of both enantiomers of 4-(2,6-dimethylheptyl)benzoic acid

Galina Dmitrievna Gamalevich 1
Galina Dmitrievna Gamalevich
, 
Edward Prokof'evich Serebryakov 1
Edward Prokof'evich Serebryakov
, 
Alexei Leonidovich Vlasyuk 2
Alexei Leonidovich Vlasyuk
10.1070/MC1998v008n01ABEH000890
Published 1998-02-28
Communication , Volume 8, Issue 1, 8-9
4
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Gamalevich G. D., Serebryakov E. P., Vlasyuk A. L. Lipase-mediated stereodivergent synthesis of both enantiomers of 4-(2,6-dimethylheptyl)benzoic acid // Mendeleev Communications. 1998. Vol. 8. No. 1. pp. 8-9.
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Gamalevich G. D., Serebryakov E. P., Vlasyuk A. L. Lipase-mediated stereodivergent synthesis of both enantiomers of 4-(2,6-dimethylheptyl)benzoic acid // Mendeleev Communications. 1998. Vol. 8. No. 1. pp. 8-9.
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TY - JOUR
DO - 10.1070/MC1998v008n01ABEH000890
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n01ABEH000890
TI - Lipase-mediated stereodivergent synthesis of both enantiomers of 4-(2,6-dimethylheptyl)benzoic acid
T2 - Mendeleev Communications
AU - Gamalevich, Galina Dmitrievna
AU - Serebryakov, Edward Prokof'evich
AU - Vlasyuk, Alexei Leonidovich
PY - 1998
DA - 1998/02/28
PB - Mendeleev Communications
SP - 8-9
IS - 1
VL - 8
ER -
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@article{1998_Gamalevich,
author = {Galina Dmitrievna Gamalevich and Edward Prokof'evich Serebryakov and Alexei Leonidovich Vlasyuk},
title = {Lipase-mediated stereodivergent synthesis of both enantiomers of 4-(2,6-dimethylheptyl)benzoic acid},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n01ABEH000890},
number = {1},
pages = {8--9},
doi = {10.1070/MC1998v008n01ABEH000890}
}
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Gamalevich, Galina Dmitrievna, et al. “Lipase-mediated stereodivergent synthesis of both enantiomers of 4-(2,6-dimethylheptyl)benzoic acid.” Mendeleev Communications, vol. 8, no. 1, Feb. 1998, pp. 8-9. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n01ABEH000890.

Abstract

(S)- and (R)-Enantiomers of methyl 4-(3-hydroxy-2-methylpropyl)benzoate, obtained by enzymatic kinetic resolution of the related racemic arene(tricarbonyl)chromium complex in the vinyl acetate–PPL/Et2O acylating system, have been converted in four steps into the (R)- and (S)-enantiomers of the title acid, respectively.

References

1.
K. Nakamoto, T. Suzuki, S. Abe, K. Hayashi, A. Kajivara, I. Yamatsu, I. Otsuka and H. Shiojiri, Eur. Pat. Appl., EP 194693 (1986).
2.
10.1070/MC1998v008n01ABEH000890_bib2
Kryshtal
Izv. Akad. Nauk, Ser. Khim., 1993
3.
E. P. Serebryakov, G. D. Gamalevich, A. V. Ignatenko, A. L. Vlasyuk, T. V. Filatova, V. V. Tertov and A. N. Orekhov (in preparation for Bioorg. & Med. Chem.).
4.
10.1070/MC1998v008n01ABEH000890_bib4
Kryshtal
Zh. Org. Khim., 1994
5.
10.1070/MC1998v008n01ABEH000890_bib5
Gamalevich
Izv. Akad. Nauk, Ser. Khim., 1995
7.
10.1070/MC1998v008n01ABEH000890_bib7
Gamalevich
Izv. Akad. Nauk, Ser. Khim., 1997
8.
Quantitative analyses of biochemical kinetic resolutions of enantiomers
Chen C.S., Fujimoto Y., Girdaukas G., Sih C.J.
Journal of the American Chemical Society, 1982