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Unexpected synthesis of 2-(3-hydroxymethyl-3,3-pentamethyleneacetonyl)-2-trifluoromethylimidazolidine

Vyacheslav Yakovlevich Sosnovskikh
Mikhail Yur'evich Mel'nikov 1
Mikhail Yur'evich Mel'nikov
Published 1998-02-28
CommunicationVolume 8, Issue 1, 19-20
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Sosnovskikh V. Y., Mel'nikov M. Y. Unexpected synthesis of 2-(3-hydroxymethyl-3,3-pentamethyleneacetonyl)-2-trifluoromethylimidazolidine // Mendeleev Communications. 1998. Vol. 8. No. 1. pp. 19-20.
GOST all authors (up to 50) Copy
Sosnovskikh V. Y., Mel'nikov M. Y. Unexpected synthesis of 2-(3-hydroxymethyl-3,3-pentamethyleneacetonyl)-2-trifluoromethylimidazolidine // Mendeleev Communications. 1998. Vol. 8. No. 1. pp. 19-20.
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TY - JOUR
DO - 10.1070/MC1998v008n01ABEH000883
UR - https://mendcomm.colab.ws/publications/10.1070/MC1998v008n01ABEH000883
TI - Unexpected synthesis of 2-(3-hydroxymethyl-3,3-pentamethyleneacetonyl)-2-trifluoromethylimidazolidine
T2 - Mendeleev Communications
AU - Sosnovskikh, Vyacheslav Yakovlevich
AU - Mel'nikov, Mikhail Yur'evich
PY - 1998
DA - 1998/02/28
PB - Mendeleev Communications
SP - 19-20
IS - 1
VL - 8
ER -
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@article{1998_Sosnovskikh,
author = {Vyacheslav Yakovlevich Sosnovskikh and Mikhail Yur'evich Mel'nikov},
title = {Unexpected synthesis of 2-(3-hydroxymethyl-3,3-pentamethyleneacetonyl)-2-trifluoromethylimidazolidine},
journal = {Mendeleev Communications},
year = {1998},
volume = {8},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1998v008n01ABEH000883},
number = {1},
pages = {19--20},
doi = {10.1070/MC1998v008n01ABEH000883}
}
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Sosnovskikh, Vyacheslav Yakovlevich, and Mikhail Yur'evich Mel'nikov. “Unexpected synthesis of 2-(3-hydroxymethyl-3,3-pentamethyleneacetonyl)-2-trifluoromethylimidazolidine.” Mendeleev Communications, vol. 8, no. 1, Feb. 1998, pp. 19-20. https://mendcomm.colab.ws/publications/10.1070/MC1998v008n01ABEH000883.

Abstract

The reaction of 2-amino-6-hydroxy-5,5-pentamethylene-1,1,1-trifluoro-2-hexen-4-one with ethylenediamine, in contrast to the similar reaction involving 2-amino-6-hydroxy-5,5-dimethyl-1,1,1-trifluoro-2-hexen-4-one, leads to 2-(3-hydroxymethyl-3,3-pentamethyleneacetonyl)-2-trifluoromethylimidazolidine.

References

1.
10.1070/MC1998v008n01ABEH000883_bib1
Pashkevich
Izv. Akad. Nauk SSSR, Ser. Khim., 1981
2.
V. Ya. Sosnovskikh and M. Yu. Mel’nikov, Zh. Org. Khim., 1998, in press.