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Z/E isomerisation of ferrocenyl- and arylmethylidene-substituted derivatives of quinuclidine and camphor

Elena Ivanovna Klimova 1
Elena Ivanovna Klimova
, 
Tatiana Klimova-Berestneva 1
Tatiana Klimova-Berestneva
, 
Marcos Martinez Garcia 2
Marcos Martinez Garcia
, 
Natalya Nikitichna Meleshonkova 3
Natalya Nikitichna Meleshonkova
, 
Lena R Ruis 1
Lena R Ruis
10.1070/MC1997v007n06ABEH000837
Published 1997-12-31
Communication , Volume 7, Issue 6, 233-235
5
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Klimova E. I. et al. Z/E isomerisation of ferrocenyl- and arylmethylidene-substituted derivatives of quinuclidine and camphor // Mendeleev Communications. 1997. Vol. 7. No. 6. pp. 233-235.
GOST all authors (up to 50) Copy
Klimova E. I., Klimova-Berestneva T., Martinez Garcia M., Meleshonkova N. N., Ruis L. R. Z/E isomerisation of ferrocenyl- and arylmethylidene-substituted derivatives of quinuclidine and camphor // Mendeleev Communications. 1997. Vol. 7. No. 6. pp. 233-235.
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TY - JOUR
DO - 10.1070/MC1997v007n06ABEH000837
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n06ABEH000837
TI - Z/E isomerisation of ferrocenyl- and arylmethylidene-substituted derivatives of quinuclidine and camphor
T2 - Mendeleev Communications
AU - Klimova, Elena Ivanovna
AU - Klimova-Berestneva, Tatiana
AU - Martinez Garcia, Marcos
AU - Meleshonkova, Natalya Nikitichna
AU - Ruis, Lena R
PY - 1997
DA - 1997/12/31
PB - Mendeleev Communications
SP - 233-235
IS - 6
VL - 7
ER -
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@article{1997_Klimova,
author = {Elena Ivanovna Klimova and Tatiana Klimova-Berestneva and Marcos Martinez Garcia and Natalya Nikitichna Meleshonkova and Lena R Ruis},
title = {Z/E isomerisation of ferrocenyl- and arylmethylidene-substituted derivatives of quinuclidine and camphor},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n06ABEH000837},
number = {6},
pages = {233--235},
doi = {10.1070/MC1997v007n06ABEH000837}
}
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Klimova, Elena Ivanovna, et al. “Z/E isomerisation of ferrocenyl- and arylmethylidene-substituted derivatives of quinuclidine and camphor.” Mendeleev Communications, vol. 7, no. 6, Dec. 1997, pp. 233-235. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n06ABEH000837.

Abstract

2-Ferrocenylmethylidene-3-methyl-1-azoniabicyclo[2,2,2]octane-3-cation and 2-ferrocenylmethylidene-1,2,7,7-tetramethylbicyclo-[2,2,1]heptane-2-cation tetrafluoroborates and tetraphenylborates having bulky substituents in their molecules have been found to isomerise in solutions with inversion of configuration at the double bond. Tetrafluoroborates and tetraphenylborates of the 3-methyl-2,3-(1-piperidinium-1,4-diyl)-1-ferrocenylallyl cation and the 3-methyl-2,3-(1,2,2-trimethylcyclopentane-1,3-diyl)-1-ferrocenylallyl cation with bulky substituents at the C1 atom isomerise in solutions with inversion of configuration at the C1–C2 bond.

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