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A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters

Viktor Mikhailovich Mamaev 1
Viktor Mikhailovich Mamaev
,  , 
Vahan Vladimirovich Simonyan 1
Vahan Vladimirovich Simonyan
, 
Elena Vladimirovna Zernova 1
Elena Vladimirovna Zernova
, 
Andrei Viktorovich Prisyajnuk 2
Andrei Viktorovich Prisyajnuk
, 
Yuri Aleksandrovich Ustynyuk 1
Yuri Aleksandrovich Ustynyuk
10.1070/MC1997v007n06ABEH000801
Published 1997-12-31
Communication , Volume 7, Issue 6, 246-248
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Mamaev V. M. et al. A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters // Mendeleev Communications. 1997. Vol. 7. No. 6. pp. 246-248.
GOST all authors (up to 50) Copy
Mamaev V. M., Gloriozov I. P., Simonyan V. V., Zernova E. V., Prisyajnuk A. V., Ustynyuk Y. A. A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters // Mendeleev Communications. 1997. Vol. 7. No. 6. pp. 246-248.
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TY - JOUR
DO - 10.1070/MC1997v007n06ABEH000801
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n06ABEH000801
TI - A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters
T2 - Mendeleev Communications
AU - Mamaev, Viktor Mikhailovich
AU - Gloriozov, Igor Pavlovich
AU - Simonyan, Vahan Vladimirovich
AU - Zernova, Elena Vladimirovna
AU - Prisyajnuk, Andrei Viktorovich
AU - Ustynyuk, Yuri Aleksandrovich
PY - 1997
DA - 1997/12/31
PB - Mendeleev Communications
SP - 246-248
IS - 6
VL - 7
ER -
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@article{1997_Mamaev,
author = {Viktor Mikhailovich Mamaev and Igor Pavlovich Gloriozov and Vahan Vladimirovich Simonyan and Elena Vladimirovna Zernova and Andrei Viktorovich Prisyajnuk and Yuri Aleksandrovich Ustynyuk},
title = {A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n06ABEH000801},
number = {6},
pages = {246--248},
doi = {10.1070/MC1997v007n06ABEH000801}
}
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Mamaev, Viktor Mikhailovich, et al. “A theoretical study of the mechanism of oxidative dihydrogen addition to palladium clusters.” Mendeleev Communications, vol. 7, no. 6, Dec. 1997, pp. 246-248. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n06ABEH000801.

Abstract

The mechanism of dihydrogen oxidative addition to the simplest palladium cluster has been analysed within the framework of the reaction-path Hamiltonian approximation; a planar dihydride complex has been found to form without the potential energy barrier and intramolecular degenerate exchange of the protons in the complex has been investigated.

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