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The first example of the generation and trapping of diazospiropentane by unsaturated compounds

, 
Evgenii Vladimirovich Shulishov 1
Evgenii Vladimirovich Shulishov
, 
Galina Petrovna Okonnishnikova 1
Galina Petrovna Okonnishnikova
, 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
10.1070/MC1997v007n05ABEH000828
Published 1997-10-30
Communication , Volume 7, Issue 5, 200-201
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Tomilov Y. V. et al. The first example of the generation and trapping of diazospiropentane by unsaturated compounds // Mendeleev Communications. 1997. Vol. 7. No. 5. pp. 200-201.
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Tomilov Y. V., Shulishov E. V., Okonnishnikova G. P., Nefedov O. M. The first example of the generation and trapping of diazospiropentane by unsaturated compounds // Mendeleev Communications. 1997. Vol. 7. No. 5. pp. 200-201.
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TY - JOUR
DO - 10.1070/MC1997v007n05ABEH000828
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000828
TI - The first example of the generation and trapping of diazospiropentane by unsaturated compounds
T2 - Mendeleev Communications
AU - Tomilov, Yury Vasil'evich
AU - Shulishov, Evgenii Vladimirovich
AU - Okonnishnikova, Galina Petrovna
AU - Nefedov, Oleg Matveevich
PY - 1997
DA - 1997/10/30
PB - Mendeleev Communications
SP - 200-201
IS - 5
VL - 7
ER -
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@article{1997_Tomilov,
author = {Yury Vasil'evich Tomilov and Evgenii Vladimirovich Shulishov and Galina Petrovna Okonnishnikova and Oleg Matveevich Nefedov},
title = {The first example of the generation and trapping of diazospiropentane by unsaturated compounds},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000828},
number = {5},
pages = {200--201},
doi = {10.1070/MC1997v007n05ABEH000828}
}
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Cite this
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Tomilov, Yury Vasil'evich, et al. “The first example of the generation and trapping of diazospiropentane by unsaturated compounds.” Mendeleev Communications, vol. 7, no. 5, Oct. 1997, pp. 200-201. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000828.

Abstract

Alkaline hydrolysis of N-spiropentyl-N-nitrosourea at –50 °C generates unknown diazospiropentane in situ, which is trapped with methyl methacrylate or 3,3-dimethylcyclopropene yielding the corresponding 1-pyrazolines with a spiropentane fragment in the molecule. Some chemical transformations of the products obtained are performed.

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