Home / Publications / Formation of heterobinuclear μ-nitrido complexes with a Mn–N–Fe moiety by reaction of nitrido(octaphenyltetraazaporphyrinato)manganese(V) with iron(III) porphyrins

Formation of heterobinuclear μ-nitrido complexes with a Mn–N–Fe moiety by reaction of nitrido(octaphenyltetraazaporphyrinato)manganese(V) with iron(III) porphyrins

, 
Mahmud Hamdush 2
Mahmud Hamdush
, 
Heiner Homborg 3
Heiner Homborg
10.1070/MC1997v007n05ABEH000819
Published 1997-10-30
Communication , Volume 7, Issue 5, 196-198
24
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Stuzhin P. A., Hamdush M., Homborg H. Formation of heterobinuclear μ-nitrido complexes with a Mn–N–Fe moiety by reaction of nitrido(octaphenyltetraazaporphyrinato)manganese(V) with iron(III) porphyrins // Mendeleev Communications. 1997. Vol. 7. No. 5. pp. 196-198.
GOST all authors (up to 50) Copy
Stuzhin P. A., Hamdush M., Homborg H. Formation of heterobinuclear μ-nitrido complexes with a Mn–N–Fe moiety by reaction of nitrido(octaphenyltetraazaporphyrinato)manganese(V) with iron(III) porphyrins // Mendeleev Communications. 1997. Vol. 7. No. 5. pp. 196-198.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1997v007n05ABEH000819
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000819
TI - Formation of heterobinuclear μ-nitrido complexes with a Mn–N–Fe moiety by reaction of nitrido(octaphenyltetraazaporphyrinato)manganese(V) with iron(III) porphyrins
T2 - Mendeleev Communications
AU - Stuzhin, Pavel Anatolievich
AU - Hamdush, Mahmud
AU - Homborg, Heiner
PY - 1997
DA - 1997/10/30
PB - Mendeleev Communications
SP - 196-198
IS - 5
VL - 7
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1997_Stuzhin,
author = {Pavel Anatolievich Stuzhin and Mahmud Hamdush and Heiner Homborg},
title = {Formation of heterobinuclear μ-nitrido complexes with a Mn–N–Fe moiety by reaction of nitrido(octaphenyltetraazaporphyrinato)manganese(V) with iron(III) porphyrins},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000819},
number = {5},
pages = {196--198},
doi = {10.1070/MC1997v007n05ABEH000819}
}
MLA
Cite this
MLA Copy
Stuzhin, Pavel Anatolievich, et al. “Formation of heterobinuclear μ-nitrido complexes with a Mn–N–Fe moiety by reaction of nitrido(octaphenyltetraazaporphyrinato)manganese(V) with iron(III) porphyrins.” Mendeleev Communications, vol. 7, no. 5, Oct. 1997, pp. 196-198. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000819.

Abstract

Nitrido(octaphenyltetraazaporphyrinato)manganese(V) (N≡MnOPTAP) obtained by treatment of chlorine on acido(octaphenyltetraazaporphyrinato) manganese(III) [(X)MnOPTAP; X = Cl, AcO, HSO4] in chloroform solution saturated with ammonia, reacts with acido(octaphenyltetraazaporphyrinato)iron(III) [(X)FeOPTAP; X = Cl, Br, AcO] forming the heterometallic μ-nitrido complex μ-(MnNFe)(OPTAP)2; μ-nitrido complexes with a dissimilar porphyrin ligand on each metal have also been prepared.

References

3.
Nitrido-bridged iron phthalocyanine dimers: synthesis and characterization
Goedkent V.L., Ercolani C.
Journal of the Chemical Society Chemical Communications, 1984
7.
Formation of nitridoiron(V) porphyrins detected by resonance Raman spectroscopy
Wagner W.D., Nakamoto K.
Journal of the American Chemical Society, 1988