Home / Publications / Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system

Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system

Anatolii Savel'evich Morkovnik 1
Anatolii Savel'evich Morkovnik
10.1070/MC1997v007n05ABEH000817
Published 1997-10-30
Communication , Volume 7, Issue 5, 175-176
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Morkovnik A. S. Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system // Mendeleev Communications. 1997. Vol. 7. No. 5. pp. 175-176.
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Morkovnik A. S. Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system // Mendeleev Communications. 1997. Vol. 7. No. 5. pp. 175-176.
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TY - JOUR
DO - 10.1070/MC1997v007n05ABEH000817
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000817
TI - Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system
T2 - Mendeleev Communications
AU - Morkovnik, Anatolii Savel'evich
PY - 1997
DA - 1997/10/30
PB - Mendeleev Communications
SP - 175-176
IS - 5
VL - 7
ER -
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@article{1997_Morkovnik,
author = {Anatolii Savel'evich Morkovnik},
title = {Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000817},
number = {5},
pages = {175--176},
doi = {10.1070/MC1997v007n05ABEH000817}
}
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Morkovnik, Anatolii Savel'evich. “Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system.” Mendeleev Communications, vol. 7, no. 5, Oct. 1997, pp. 175-176. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000817.
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Abstract

Nitration of 1,2,2,3-tetrasubstituted 5-triphenylmethylbenzimidazolines using an Ag+/NO2−system shows an unexpected (for benzimidazolines) orientation of the nitro group into position 7, which may be due to the strong steric influence of the rather bulky triphenylmethyl substituent.

References

1.
A. S. Morkovnik, Dr. Sci. Thesis, Rostov-on-Don, 1991.
2.
10.1070/MC1997v007n05ABEH000817_bib2
Eberson
Electron Transfer Reactions in Organic Chemistry, 1987
3.
10.1070/MC1997v007n05ABEH000817_bib3
Morkovnik
Khim. Geterotsikl. Soedin., 1995
4.
10.1070/MC1997v007n05ABEH000817_bib4
Morkovnik
Zh. Neorg. Khim., 1987