Home / Publications / Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system

Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system

Anatolii Savel'evich Morkovnik 1
Anatolii Savel'evich Morkovnik
10.1070/MC1997v007n05ABEH000817
Published 1997-10-30
Communication , Volume 7, Issue 5, 175-176
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Morkovnik A. S. Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system // Mendeleev Communications. 1997. Vol. 7. No. 5. pp. 175-176.
GOST all authors (up to 50) Copy
Morkovnik A. S. Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system // Mendeleev Communications. 1997. Vol. 7. No. 5. pp. 175-176.
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TY - JOUR
DO - 10.1070/MC1997v007n05ABEH000817
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000817
TI - Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system
T2 - Mendeleev Communications
AU - Morkovnik, Anatolii Savel'evich
PY - 1997
DA - 1997/10/30
PB - Mendeleev Communications
SP - 175-176
IS - 5
VL - 7
ER -
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@article{1997_Morkovnik,
author = {Anatolii Savel'evich Morkovnik},
title = {Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000817},
number = {5},
pages = {175--176},
doi = {10.1070/MC1997v007n05ABEH000817}
}
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Morkovnik, Anatolii Savel'evich. “Steric control in the ion radical nitration of 5-triphenylmethylbenzimidazolines using a silver/nitrite system.” Mendeleev Communications, vol. 7, no. 5, Oct. 1997, pp. 175-176. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n05ABEH000817.

Abstract

Nitration of 1,2,2,3-tetrasubstituted 5-triphenylmethylbenzimidazolines using an Ag+/NO2−system shows an unexpected (for benzimidazolines) orientation of the nitro group into position 7, which may be due to the strong steric influence of the rather bulky triphenylmethyl substituent.

References

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A. S. Morkovnik, Dr. Sci. Thesis, Rostov-on-Don, 1991.
2.
10.1070/MC1997v007n05ABEH000817_bib2
Eberson
Electron Transfer Reactions in Organic Chemistry, 1987
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10.1070/MC1997v007n05ABEH000817_bib3
Morkovnik
Khim. Geterotsikl. Soedin., 1995
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10.1070/MC1997v007n05ABEH000817_bib4
Morkovnik
Zh. Neorg. Khim., 1987