Abstract
SAXS investigations have shown that proton hydratosolvates in organic solutions of strong acids HAn form nanomicelle-like associates; the dependence of the size of the ‘nanomicelle’ (35–60 Å), their degree of shape distortion and tendency towards further aggregation on HAn concentration, the nature of An– and solvent basicity are discussed.
References
1.
10.1070/MC1997v007n05ABEH000799_bib1
Zolotov
Ekstraktsiya galogenidnykh kompleksov metallov (Extraction of Metal Halide Complexes),
1973
2.
10.1070/MC1997v007n05ABEH000799_bib2
Stoyanov
Zh. Strukt. Khim.,
1993
3.
E. S. Stoyanov, in Value Adding through Solvent Extraction, eds. D. C. Shallcross, R. Paimin and L. M. Prvcic, University of Melbourne, Australia (Proceedings of ISEC’96 conf.), 1996, vol. 1, p. 273.
4.
Glatter O.
Journal of Applied Crystallography,
1980
5.
Kolomiichuk V.N.
Reaction Kinetics and Catalysis Letters,
1982
6.
10.1070/MC1997v007n05ABEH000799_bib6
Stoyanov
Zh. Neorg. Khim.,
1981
7.
Smol'skaya E.L., Stoyanov E.S., Egutkin N.L.
Solvent Extraction and Ion Exchange,
1991
8.
Kertes A.S., Kertes V.
Journal of Applied Chemistry,
2007
9.
10.1070/MC1997v007n05ABEH000799_bib9
Stoyanov
Zh. Neorg. Khim.,
1992