Home / Publications / Ylides from dihalocarbenes and esters of N-benzhydrylidene amino acids: halogen-dependent reaction pathways

Ylides from dihalocarbenes and esters of N-benzhydrylidene amino acids: halogen-dependent reaction pathways

Alexander Fedorovich Khlebnikov 1
Alexander Fedorovich Khlebnikov
,  , 
Rafael Ravilovich Kostikov 1
Rafael Ravilovich Kostikov
10.1070/MC1997v007n04ABEH000797
Published 1997-08-30
Communication , Volume 7, Issue 4, 145-147
10
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Khlebnikov A. F., Novikov M. S., Kostikov R. R. Ylides from dihalocarbenes and esters of N-benzhydrylidene amino acids: halogen-dependent reaction pathways // Mendeleev Communications. 1997. Vol. 7. No. 4. pp. 145-147.
GOST all authors (up to 50) Copy
Khlebnikov A. F., Novikov M. S., Kostikov R. R. Ylides from dihalocarbenes and esters of N-benzhydrylidene amino acids: halogen-dependent reaction pathways // Mendeleev Communications. 1997. Vol. 7. No. 4. pp. 145-147.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1997v007n04ABEH000797
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000797
TI - Ylides from dihalocarbenes and esters of N-benzhydrylidene amino acids: halogen-dependent reaction pathways
T2 - Mendeleev Communications
AU - Khlebnikov, Alexander Fedorovich
AU - Novikov, Mikhail Sergeyevich
AU - Kostikov, Rafael Ravilovich
PY - 1997
DA - 1997/08/30
PB - Mendeleev Communications
SP - 145-147
IS - 4
VL - 7
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1997_Khlebnikov,
author = {Alexander Fedorovich Khlebnikov and Mikhail Sergeyevich Novikov and Rafael Ravilovich Kostikov},
title = {Ylides from dihalocarbenes and esters of N-benzhydrylidene amino acids: halogen-dependent reaction pathways},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000797},
number = {4},
pages = {145--147},
doi = {10.1070/MC1997v007n04ABEH000797}
}
MLA
Cite this
MLA Copy
Khlebnikov, Alexander Fedorovich, et al. “Ylides from dihalocarbenes and esters of N-benzhydrylidene amino acids: halogen-dependent reaction pathways.” Mendeleev Communications, vol. 7, no. 4, Aug. 1997, pp. 145-147. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000797.

Abstract

The nature of the halogen dramatically affects the properties of azomethine ylides derived from dihalocarbenes and the benzophenone Schiff bases of amino acid esters: dichloro- and chlorofluoroylides cyclise to give gem-dihaloaziridines 2a–e, while difluoroylides characteristically undergo ylide–ylide isomerisation and 1,3-dipolar cycloaddition.

References

1.
10.1070/MC1997v007n04ABEH000797_bib1
Khlebnikov
Izv. Akad. Nauk, Ser. Khim., 1993
2.
10.1070/MC1997v007n04ABEH000797_bib2
Khlebnikov
1996
4.
10.1070/MC1997v007n04ABEH000797_bib4
Deyrup
Small Ring Heterocycles, 1983
5.
10.1070/MC1997v007n04ABEH000797_bib5
Khlebnikov
Zh. Org. Khim., 1996
6.
New pathway for the reaction of difluorocarbene with imines
McCarthy J.R., Barney C.L., O'Donnell M.J., Huffman J.C.
Journal of the Chemical Society Chemical Communications, 1987
7.
Fluorinated Carbenes
Brahms D.L., Dailey W.P.
Chemical Reviews, 1996
8.
Acidities of glycine Schiff bases and alkylation of their conjugate bases
O'Donnell M.J., Bennett W.D., Bruder W.A., Jacobsen W.N., Knuth K., LeClef B., Polt R.L., Bordwell F.G., Mrozack S.R., Cripe T.A.
Journal of the American Chemical Society, 1988
11.
10.1070/MC1997v007n04ABEH000797_bib11
Balcerzak
J. Chem. Research (S), 1994
12.
Die Reduktion von CBr2F2 durch Blei - ein neuartiger Weg zum Difluorcarben / The Reduction of CBr2F2 by Lead -a Novel Pathway to Difluorocarbene
Fritz H.P., Kornrumpf W.
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1981
14.
10.1070/MC1997v007n04ABEH000797_bib14
Novikov
Zh. Org. Khim., 1996