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Synthesis of diethyl oxo phosphonates from monoterpene ketones – carvone, pinocarvone and 2-caren-4-one

Vasilii Dmitrievich Kolesnik 1
Vasilii Dmitrievich Kolesnik
Makhmut Minakhmetovich Shakirov 2
Makhmut Minakhmetovich Shakirov
Alexey Vasil'evich Tkachev 2
Alexey Vasil'evich Tkachev
Published 1997-08-30
CommunicationVolume 7, Issue 4, 141-143
7
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Kolesnik V. D., Shakirov M. M., Tkachev A. V. Synthesis of diethyl oxo phosphonates from monoterpene ketones – carvone, pinocarvone and 2-caren-4-one // Mendeleev Communications. 1997. Vol. 7. No. 4. pp. 141-143.
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Kolesnik V. D., Shakirov M. M., Tkachev A. V. Synthesis of diethyl oxo phosphonates from monoterpene ketones – carvone, pinocarvone and 2-caren-4-one // Mendeleev Communications. 1997. Vol. 7. No. 4. pp. 141-143.
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TY - JOUR
DO - 10.1070/MC1997v007n04ABEH000764
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000764
TI - Synthesis of diethyl oxo phosphonates from monoterpene ketones – carvone, pinocarvone and 2-caren-4-one
T2 - Mendeleev Communications
AU - Kolesnik, Vasilii Dmitrievich
AU - Shakirov, Makhmut Minakhmetovich
AU - Tkachev, Alexey Vasil'evich
PY - 1997
DA - 1997/08/30
PB - Mendeleev Communications
SP - 141-143
IS - 4
VL - 7
ER -
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@article{1997_Kolesnik,
author = {Vasilii Dmitrievich Kolesnik and Makhmut Minakhmetovich Shakirov and Alexey Vasil'evich Tkachev},
title = {Synthesis of diethyl oxo phosphonates from monoterpene ketones – carvone, pinocarvone and 2-caren-4-one},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000764},
number = {4},
pages = {141--143},
doi = {10.1070/MC1997v007n04ABEH000764}
}
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Kolesnik, Vasilii Dmitrievich, et al. “Synthesis of diethyl oxo phosphonates from monoterpene ketones – carvone, pinocarvone and 2-caren-4-one.” Mendeleev Communications, vol. 7, no. 4, Aug. 1997, pp. 141-143. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000764.

Abstract

Reaction of α,β-unsaturated monoterpenic ketones – carvone, pinocarvone and 2-caren-4-one – with the sodium salt of diethylphosphite in diethylphosphite media results in regioselective addition to the conjugated carbon–carbon double bond and formation of the corresponding oxophosphonates.

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