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Synthesis of 1H- and 1-vinyl-2-pyridylpyrroles by the Trofimov reaction

Olga Vital'evna Petrova 1
Olga Vital'evna Petrova
, 
Albina Ivanovna Mikhaleva 1
Albina Ivanovna Mikhaleva
,  , 
Elena Yur'evna Schmidt 1
Elena Yur'evna Schmidt
, 
Èmilia Ivanovna Kositsyna 1
Èmilia Ivanovna Kositsyna
10.1070/MC1997v007n04ABEH000752
Published 1997-08-30
Communication , Volume 7, Issue 4, 162-163
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Petrova O. V. et al. Synthesis of 1H- and 1-vinyl-2-pyridylpyrroles by the Trofimov reaction // Mendeleev Communications. 1997. Vol. 7. No. 4. pp. 162-163.
GOST all authors (up to 50) Copy
Petrova O. V., Mikhaleva A. I., Sobenina L. N., Schmidt E. Y., Kositsyna È. I. Synthesis of 1H- and 1-vinyl-2-pyridylpyrroles by the Trofimov reaction // Mendeleev Communications. 1997. Vol. 7. No. 4. pp. 162-163.
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TY - JOUR
DO - 10.1070/MC1997v007n04ABEH000752
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000752
TI - Synthesis of 1H- and 1-vinyl-2-pyridylpyrroles by the Trofimov reaction
T2 - Mendeleev Communications
AU - Petrova, Olga Vital'evna
AU - Mikhaleva, Albina Ivanovna
AU - Sobenina, Lyubov Nikolaevna
AU - Schmidt, Elena Yur'evna
AU - Kositsyna, Èmilia Ivanovna
PY - 1997
DA - 1997/08/30
PB - Mendeleev Communications
SP - 162-163
IS - 4
VL - 7
ER -
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@article{1997_Petrova,
author = {Olga Vital'evna Petrova and Albina Ivanovna Mikhaleva and Lyubov Nikolaevna Sobenina and Elena Yur'evna Schmidt and Èmilia Ivanovna Kositsyna},
title = {Synthesis of 1H- and 1-vinyl-2-pyridylpyrroles by the Trofimov reaction},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000752},
number = {4},
pages = {162--163},
doi = {10.1070/MC1997v007n04ABEH000752}
}
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Petrova, Olga Vital'evna, et al. “Synthesis of 1H- and 1-vinyl-2-pyridylpyrroles by the Trofimov reaction.” Mendeleev Communications, vol. 7, no. 4, Aug. 1997, pp. 162-163. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000752.

Abstract

A one-pot synthesis of 2-(2-pyridyl)-1H-pyrrole and 1-vinyl-2-(2-pyridyl)-, 1-vinyl-2-(3-pyridyl)- and 1-vinyl-2-(4-pyridyl)-pyrroles from oximes of 2-acetyl-, 3-acetyl- and 4-acetylpyridine and acetylene under pressure (16–25 atm) in a KOH/DMSO system has been carried out (105–120 °C, 3 h) to reveal for the first time the applicability of the Trofimov reaction for the preparation of alkaloids of the nicotine series.

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