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A novel stereoselective and catalytic C–C coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system

Sergei Anatol'evich Mitchenko 1
Sergei Anatol'evich Mitchenko
,  ,  , 
Yuri Aleksandrovich Ustynyuk 3
Yuri Aleksandrovich Ustynyuk
10.1070/MC1997v007n04ABEH000715
Published 1997-08-30
Communication , Volume 7, Issue 4, 130-131
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Mitchenko S. A. et al. A novel stereoselective and catalytic C–C coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system // Mendeleev Communications. 1997. Vol. 7. No. 4. pp. 130-131.
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Mitchenko S. A., Ananikov V. P., Beletskaya I. P., Ustynyuk Y. A. A novel stereoselective and catalytic C–C coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system // Mendeleev Communications. 1997. Vol. 7. No. 4. pp. 130-131.
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TY - JOUR
DO - 10.1070/MC1997v007n04ABEH000715
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000715
TI - A novel stereoselective and catalytic C–C coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system
T2 - Mendeleev Communications
AU - Mitchenko, Sergei Anatol'evich
AU - Ananikov, Valentin Pavlovich
AU - Beletskaya, Irina Petrovna
AU - Ustynyuk, Yuri Aleksandrovich
PY - 1997
DA - 1997/08/30
PB - Mendeleev Communications
SP - 130-131
IS - 4
VL - 7
ER -
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@article{1997_Mitchenko,
author = {Sergei Anatol'evich Mitchenko and Valentin Pavlovich Ananikov and Irina Petrovna Beletskaya and Yuri Aleksandrovich Ustynyuk},
title = {A novel stereoselective and catalytic C–C coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000715},
number = {4},
pages = {130--131},
doi = {10.1070/MC1997v007n04ABEH000715}
}
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Mitchenko, Sergei Anatol'evich, et al. “A novel stereoselective and catalytic C–C coupling reaction: acetylene dimerization accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene in the PtIV–I––I2–MeOH system.” Mendeleev Communications, vol. 7, no. 4, Aug. 1997, pp. 130-131. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n04ABEH000715.

Abstract

A new catalytic reaction – dimerization of acetylene accompanied by addition of iodine to yield (E,E)-1,4-diiodobuta-1,3-diene at 30 °C in a methanolic solution of NaI, PtIV and I2 – has been found; a plausible reaction mechanism involves intermediate formation of a cis-divinyl derivative of platinum(IV) through two subsequent triple bond iodoplatination steps followed by reductive elimination of the final product.

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