Home / Publications / Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process

Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process

Rosa Becerra 1
Rosa Becerra
, 
Sergei Evgen'evich Boganov 2
Sergei Evgen'evich Boganov
, 
Mikhail Petrovich Egorov 2
Mikhail Petrovich Egorov
, 
Oleg Matveevich Nefedov 2
Oleg Matveevich Nefedov
, 
Robin Walsh 3
Robin Walsh
10.1070/MC1997v007n03ABEH000787
Published 1997-06-30
Communication , Volume 7, Issue 3, 87-88
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Becerra R. et al. Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process // Mendeleev Communications. 1997. Vol. 7. No. 3. pp. 87-88.
GOST all authors (up to 50) Copy
Becerra R., Boganov S. E., Egorov M. P., Nefedov O. M., Walsh R. Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process // Mendeleev Communications. 1997. Vol. 7. No. 3. pp. 87-88.
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TY - JOUR
DO - 10.1070/MC1997v007n03ABEH000787
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n03ABEH000787
TI - Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process
T2 - Mendeleev Communications
AU - Becerra, Rosa
AU - Boganov, Sergei Evgen'evich
AU - Egorov, Mikhail Petrovich
AU - Nefedov, Oleg Matveevich
AU - Walsh, Robin
PY - 1997
DA - 1997/06/30
PB - Mendeleev Communications
SP - 87-88
IS - 3
VL - 7
ER -
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@article{1997_Becerra,
author = {Rosa Becerra and Sergei Evgen'evich Boganov and Mikhail Petrovich Egorov and Oleg Matveevich Nefedov and Robin Walsh},
title = {Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n03ABEH000787},
number = {3},
pages = {87--88},
doi = {10.1070/MC1997v007n03ABEH000787}
}
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Becerra, Rosa, et al. “Direct time-resolved study of the kinetics of the gas-phase reaction of germylene with triethylgermane: a negative activation energy for the Ge–H insertion process.” Mendeleev Communications, vol. 7, no. 3, Jun. 1997, pp. 87-88. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n03ABEH000787.

Abstract

Gas-phase rate constants, obtained from 292–557 K, yield an activation energy of –10.6±1.1 kJ mol–1 for the insertion reaction of GeH2 into a Ge–H bond (of triethylgermane); these results indicate the likely involvement of an intermediate complex.

References

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