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The reactivity of calyx[4]resorcinolarene anions towards p-nitrophenyl esters of tetracoordinated phosphorus acids

Irina Sergeevna Ryzhkina 1
Irina Sergeevna Ryzhkina
, 
Lyudmila Andreevna Kudryavtseva 1
Lyudmila Andreevna Kudryavtseva
, 
Ella Khatibovna Kazakova 1
Ella Khatibovna Kazakova
, 
Alexander Romanovich Burilov 1
Alexander Romanovich Burilov
, 
Aleksandr Ivanovich Konovalov 2
Aleksandr Ivanovich Konovalov
10.1070/MC1997v007n03ABEH000713
Published 1997-06-30
Communication , Volume 7, Issue 3, 88-90
3
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Ryzhkina I. S. et al. The reactivity of calyx[4]resorcinolarene anions towards p-nitrophenyl esters of tetracoordinated phosphorus acids // Mendeleev Communications. 1997. Vol. 7. No. 3. pp. 88-90.
GOST all authors (up to 50) Copy
Ryzhkina I. S., Kudryavtseva L. A., Kazakova E. K., Burilov A. R., Konovalov A. I. The reactivity of calyx[4]resorcinolarene anions towards p-nitrophenyl esters of tetracoordinated phosphorus acids // Mendeleev Communications. 1997. Vol. 7. No. 3. pp. 88-90.
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TY - JOUR
DO - 10.1070/MC1997v007n03ABEH000713
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n03ABEH000713
TI - The reactivity of calyx[4]resorcinolarene anions towards p-nitrophenyl esters of tetracoordinated phosphorus acids
T2 - Mendeleev Communications
AU - Ryzhkina, Irina Sergeevna
AU - Kudryavtseva, Lyudmila Andreevna
AU - Kazakova, Ella Khatibovna
AU - Burilov, Alexander Romanovich
AU - Konovalov, Aleksandr Ivanovich
PY - 1997
DA - 1997/06/30
PB - Mendeleev Communications
SP - 88-90
IS - 3
VL - 7
ER -
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@article{1997_Ryzhkina,
author = {Irina Sergeevna Ryzhkina and Lyudmila Andreevna Kudryavtseva and Ella Khatibovna Kazakova and Alexander Romanovich Burilov and Aleksandr Ivanovich Konovalov},
title = {The reactivity of calyx[4]resorcinolarene anions towards p-nitrophenyl esters of tetracoordinated phosphorus acids},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n03ABEH000713},
number = {3},
pages = {88--90},
doi = {10.1070/MC1997v007n03ABEH000713}
}
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Ryzhkina, Irina Sergeevna, et al. “The reactivity of calyx[4]resorcinolarene anions towards p-nitrophenyl esters of tetracoordinated phosphorus acids.” Mendeleev Communications, vol. 7, no. 3, Jun. 1997, pp. 88-90. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n03ABEH000713.

Abstract

The results of a kinetic study have shown that the reactivity of monomeric forms of amphiphilic tetra- ([H4L]4–) and octa- ([L]8–) anions of calyx[4]resorcinolarenes (H8L) towards p-nitrophenyl esters of tetracoordinated phosphorus acids in aqueous dimethylformamide (50 vol.% of DMF) is determined by the nucleophilic centres of the anions, whereas an increase in the concentration of H8L inhibits the process, which is due to the formation of aggregates.

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