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Pyridine vapour pressure over [MPy4(NO3)2]·2Py (M = Co, Ni) clathrates

Elissa A Ukraintseva 1
Elissa A Ukraintseva
, 
Dmitrii Vasilievich Soldatov 1
Dmitrii Vasilievich Soldatov
, 
Vladimir Aleksandrovich Logvinenko 1
Vladimir Aleksandrovich Logvinenko
, 
Yurii Alekseevich Dyadin 1
Yurii Alekseevich Dyadin
10.1070/MC1997v007n03ABEH000705
Published 1997-06-30
Communication , Volume 7, Issue 3, 102-104
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Ukraintseva E. A. et al. Pyridine vapour pressure over [MPy4(NO3)2]·2Py (M = Co, Ni) clathrates // Mendeleev Communications. 1997. Vol. 7. No. 3. pp. 102-104.
GOST all authors (up to 50) Copy
Ukraintseva E. A., Soldatov D. V., Logvinenko V. A., Dyadin Y. A. Pyridine vapour pressure over [MPy4(NO3)2]·2Py (M = Co, Ni) clathrates // Mendeleev Communications. 1997. Vol. 7. No. 3. pp. 102-104.
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TY - JOUR
DO - 10.1070/MC1997v007n03ABEH000705
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n03ABEH000705
TI - Pyridine vapour pressure over [MPy4(NO3)2]·2Py (M = Co, Ni) clathrates
T2 - Mendeleev Communications
AU - Ukraintseva, Elissa A
AU - Soldatov, Dmitrii Vasilievich
AU - Logvinenko, Vladimir Aleksandrovich
AU - Dyadin, Yurii Alekseevich
PY - 1997
DA - 1997/06/30
PB - Mendeleev Communications
SP - 102-104
IS - 3
VL - 7
ER -
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@article{1997_Ukraintseva,
author = {Elissa A Ukraintseva and Dmitrii Vasilievich Soldatov and Vladimir Aleksandrovich Logvinenko and Yurii Alekseevich Dyadin},
title = {Pyridine vapour pressure over [MPy4(NO3)2]·2Py (M = Co, Ni) clathrates},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n03ABEH000705},
number = {3},
pages = {102--104},
doi = {10.1070/MC1997v007n03ABEH000705}
}
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Ukraintseva, Elissa A., et al. “Pyridine vapour pressure over [MPy4(NO3)2]·2Py (M = Co, Ni) clathrates.” Mendeleev Communications, vol. 7, no. 3, Jun. 1997, pp. 102-104. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n03ABEH000705.

Abstract

Pyridine vapour formation from the title clathrates is accompanied by the destruction of both the clathrate phase and the host complex: 1/3[MPy4(NO3)2]·2Py(solid) = 1/3[MPy3(NO3)2](solid) + Py(gas); the standard thermodynamic parameters of these processes are ΔH0= 59.5(2) and 64.6(4) kJ mol–1, ΔS2980=156.6(6) and 168(1) J mol–1 K–1, ΔG2980=12.8(2) and 14.4(6) kJ mol–1, for the Co- and Ni-clathrate, respectively.

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