Home / Publications / Unusual reaction of aziridine dimer with acetylene dicarboxylates

Unusual reaction of aziridine dimer with acetylene dicarboxylates

Remir Grigorevich Kostyanovsky 1
Remir Grigorevich Kostyanovsky
, 
Yuri Il'ich Èl'natanov 1
Yuri Il'ich Èl'natanov
, 
Ivan Ivanovich Chervin 1
Ivan Ivanovich Chervin
, 
Mikhail Yuvenal'evich Antipin 2
Mikhail Yuvenal'evich Antipin
, 
Alexey V Ivanov 3
Alexey V Ivanov
10.1070/MC1997v007n02ABEH000708
Published 1997-04-30
Communication , Volume 7, Issue 2, 56-58
1
Share
Cite this
GOST
 | 
Cite this
GOST Copy
Kostyanovsky R. G. et al. Unusual reaction of aziridine dimer with acetylene dicarboxylates // Mendeleev Communications. 1997. Vol. 7. No. 2. pp. 56-58.
GOST all authors (up to 50) Copy
Kostyanovsky R. G., Èl'natanov Y. I., Chervin I. I., Antipin M. Y., Ivanov A. V. Unusual reaction of aziridine dimer with acetylene dicarboxylates // Mendeleev Communications. 1997. Vol. 7. No. 2. pp. 56-58.
RIS
 | 
Cite this
RIS Copy
TY - JOUR
DO - 10.1070/MC1997v007n02ABEH000708
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000708
TI - Unusual reaction of aziridine dimer with acetylene dicarboxylates
T2 - Mendeleev Communications
AU - Kostyanovsky, Remir Grigorevich
AU - Èl'natanov, Yuri Il'ich
AU - Chervin, Ivan Ivanovich
AU - Antipin, Mikhail Yuvenal'evich
AU - Ivanov, Alexey V
PY - 1997
DA - 1997/04/30
PB - Mendeleev Communications
SP - 56-58
IS - 2
VL - 7
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors) Copy
@article{1997_Kostyanovsky,
author = {Remir Grigorevich Kostyanovsky and Yuri Il'ich Èl'natanov and Ivan Ivanovich Chervin and Mikhail Yuvenal'evich Antipin and Alexey V Ivanov},
title = {Unusual reaction of aziridine dimer with acetylene dicarboxylates},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000708},
number = {2},
pages = {56--58},
doi = {10.1070/MC1997v007n02ABEH000708}
}
MLA
Cite this
MLA Copy
Kostyanovsky, Remir Grigorevich, et al. “Unusual reaction of aziridine dimer with acetylene dicarboxylates.” Mendeleev Communications, vol. 7, no. 2, Apr. 1997, pp. 56-58. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000708.

Abstract

The 1-(2-aminoethyl)aziridine (aziridine dimer) 1 reacts with acetylene dicarboxylates to give 1,4-diaza- 5-oxobicyclo[4.3.0]nonanes (7-azaindolizines) 3 together with the usual enamine adducts 4; the product structures are confirmed spectroscopically and, in the 3 also by X-ray diffraction and by an independent synthesis from furan 5.

References

1.
10.1070/MC1997v007n02ABEH000708_bib1
Kostyanovsky
Izv. Akad. Nauk SSSR, Ser. Khim., 1988
2.
10.1070/MC1997v007n02ABEH000708_bib2
Bestian
Ann., 1950
3.
Reactions of some dicarbonyl compounds
Cantlon I.J., Cocker W., McMurry T.B.
Tetrahedron, 1961
4.
Fragmentation reaction of aziridinium ylids. II.
Hata Y., Watanabe M.
Tetrahedron Letters, 1972