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Intermolecular hydrogen bonds BH···HX in solution

Elena Solomonovna Shubina ¹

Elena Solomonovna Shubina

0000-0001-8057-3703

Ekaterina Vladimirovna Bakhmutova ¹

Ekaterina Vladimirovna Bakhmutova

Lylia Nail'evna Saitkulova ²

Lylia Nail'evna Saitkulova

Lina Meerovna Epstein ¹

Lina Meerovna Epstein

¹ A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

² Institute of Technical Chemistry, Ural Branch of the Russian Academy of Sciences, Perm, Russian Federation

10.1070/MC1997v007n02ABEH000692

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Published 1997-04-30

Communication , Volume 7, Issue 2, 83-84

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Shubina E. S. et al. Intermolecular hydrogen bonds BH···HX in solution // Mendeleev Communications. 1997. Vol. 7. No. 2. pp. 83-84.

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Shubina E. S., Bakhmutova E. V., Saitkulova L. N., Epstein L. M. Intermolecular hydrogen bonds BH···HX in solution // Mendeleev Communications. 1997. Vol. 7. No. 2. pp. 83-84.

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TY - JOUR

DO - 10.1070/MC1997v007n02ABEH000692

UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000692

TI - Intermolecular hydrogen bonds BH···HX in solution

T2 - Mendeleev Communications

AU - Shubina, Elena Solomonovna

AU - Bakhmutova, Ekaterina Vladimirovna

AU - Saitkulova, Lylia Nail'evna

AU - Epstein, Lina Meerovna

PY - 1997

DA - 1997/04/30

PB - Mendeleev Communications

SP - 83-84

IS - 2

VL - 7

ER -

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@article{1997_Shubina,

author = {Elena Solomonovna Shubina and Ekaterina Vladimirovna Bakhmutova and Lylia Nail'evna Saitkulova and Lina Meerovna Epstein},

title = {Intermolecular hydrogen bonds BH···HX in solution},

journal = {Mendeleev Communications},

year = {1997},

volume = {7},

publisher = {Mendeleev Communications},

month = {Apr},

url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000692},

number = {2},

pages = {83--84},

doi = {10.1070/MC1997v007n02ABEH000692}

}

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Shubina, Elena Solomonovna, et al. “Intermolecular hydrogen bonds BH···HX in solution.” Mendeleev Communications, vol. 7, no. 2, Apr. 1997, pp. 83-84. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000692.

Abstract

The interaction of proton donors with Bu₄NBH₄ and BH₃NEt₃ in hexane and dichloromethane was studied by IR and NMR spectroscopy and it was found for the first time that the proton-accepting centre of interaction of charged and neutral borohydrides with proton donors in solution is the hydrogen atom; the spectral and thermodynamic characteristics of the BH···HX hydrogen bond in solution were obtained and found, from enthalpy values, to be of medium strength.

References

10.1021/ja00097a049

Switching On and Off a New Intramolecular Hydrogen-Hydrogen Interaction and the Heterolytic Splitting of Dihydrogen. Crystal and Molecular Structure of [Ir{H(.eta.1-SC5H4NH)}2(PCy3)2]BF4.cntdot.2.7CH2Cl2

Lough A.J., Park S., Ramachandran R., Morris R.H.

Journal of the American Chemical Society, 1994

10.1039/C39940002201

A new type of intramolecular H ⋯ H ⋯ H interaction involving N–H ⋯ H(Ir)⋯ H–N atoms. Crystal and molecular structure of [IrH(η¹-SC₅H₄NH)₂(η²-SC₅H₄N)(PCy₃)]BF₄·0.72CH₂Cl₂

Park S., Ramachandran R., Lough A.J., Morris R.H.

Journal of the Chemical Society Chemical Communications, 1994

10.1021/ja00103a017

An Unusual Type of H.cntdot..cntdot..cntdot.H Interaction: Ir-H.cntdot..cntdot..cntdot.H-O and Ir-H.cntdot..cntdot..cntdot.H-N Hydrogen Bonding and Its Involvement in .sigma.-Bond Metathesis

Lee J.C., Peris E., Rheingold A.L., Crabtree R.H.

Journal of the American Chemical Society, 1994

10.1039/C39940001021

Complexation of an amide to iridium via an iminol tautomer and evidence Ir–H ⋯ H–O hydrogen bond

Lee J.C., Rheingold A.L., Muller B., Pregosin P.S., Crabtree R.H.

Journal of the Chemical Society Chemical Communications, 1994

10.1021/ja00117a017

Factors Affecting the Strength of N-H.cntdot..cntdot..cntdot.H-Ir Hydrogen Bonds

Peris E., Lee J.C., Rambo J.R., Eisenstein O., Crabtree R.H.

Journal of the American Chemical Society, 1995

10.1021/ja953094z

Spectroscopic Evidence for Intermolecular M−H···H−OR Hydrogen Bonding: Interaction of WH(CO)2(NO)L2 Hydrides with Acidic Alcohols

Shubina E.S., Belkova N.V., Krylov A.N., Vorontsov E.V., Epstein L.M., Gusev D.G., Niedermann M., Berke H.

Journal of the American Chemical Society, 1996

10.1021/ja00145a024

Theoretical Aspects of a Novel Mode of Hydrogen-Hydrogen Bonding

Liu Q., Hoffmann R.

Journal of the American Chemical Society, 1995

10.1039/c39950002175

d0 and d2 Polyhydrides as unconventional proton acceptors in lntermolecular hydrogen bonding

Peris E., Wessel J., Patel B.P., Crabtree R.H.

Journal of the Chemical Society Chemical Communications, 1995

10.1002/ange.19951072213

Eine ungewöhnliche intermolekulare Dreizentren-N-H⃛H2Re-Wasserstoffbrücke zwischen [ReH5(PPh3)3] und Indol im Kristall

Wessel J., Lee Jr. J.C., Peris E., Yap G.P., Fortin J.B., Ricci J.S., Sini G., Albinati A., Koetzle T.F., Eisenstein O., Rheingold A.L., Crabtree R.H.

Angewandte Chemie, 1995

10.

N V. Belkova, E. S. Shubina, A. V. Ionidis, L. M. Epstein, H. Jacobsen, A. Messmer H. Berke, Inorg. Chem., 1997, in press.

11.

10.1021/ja00156a032

Unconventional Hydrogen Bonds: Intermolecular B-H.cntdot..cntdot..cntdot.H-N Interactions

Richardson T., de Gala S., Crabtree R.H., Siegbahn P.E.

Journal of the American Chemical Society, 1995

12.

10.1070/MC1997v007n02ABEH000692_bib9_1

Brown

J. Chem. Soc., Chem. Commun., 1968

13.

10.1039/j19700000410

An infrared study of co-ordinated BH3 and BH2 groups as proton acceptors in hydrogen bonding

Brown M.P., Heseltine R.W., Smith P.A., Walker P.J.

Journal of the Chemical Society A Inorganic Physical Theoretical, 1970

14.

10.1016/0584-8539(74)80028-0

Hydrogen bonds between co-ordinated BH3 and BH2 groups and OH groups. Thermodynamics of formation by infrared spectroscopy

Brown M.P., Walker P.J.

Spectrochimica Acta Part A Molecular Spectroscopy, 1974

15.

10.1070/MC1997v007n02ABEH000692_bib10

Iogansen

Vodorodnaya Svyaz, 1981

16.

10.1016/0022-2860(88)80129-7

IR study of hydrogen bonds formed by π-complexes of transition metals in liquid xenon solution

Lokshin B.V., Kazarian S.G., Ginzburg A.G.

Journal of Molecular Structure, 1988

17.

10.1070/MC1997v007n02ABEH000692_bib11_2

Lokshin

Izv. Akad. Nauk SSSR, Ser. Khim., 1988

18.

10.1016/0371-1951(60)80145-2

The infra-red spectrum of thin films of sodium borohydride

Schutte C.J.

Spectrochimica Acta, 1960

19.

10.1021/j100608a012

Spectra and structure of boron-nitrogen compounds. II. Infrared and Raman spectra of trimethylamine-borane

Odom J.D., Barnes J.A., Hudgens B.A., Durig J.R.

The Journal of Physical Chemistry, 1974