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Alkylation of deactivated arenes by alkanes in the presence of aprotic organic superacid CBr4·2AlBr3

Alexander Vyacheslavovich Orlinkov 1
Alexander Vyacheslavovich Orlinkov
, 
Irena Sergeevna Akhrem 1
Irena Sergeevna Akhrem
, 
Lyudmila Vyacheslavovna Afanas'eva 1
Lyudmila Vyacheslavovna Afanas'eva
, 
Eugeny Ivanovich Mysov 1
Eugeny Ivanovich Mysov
, 
Mark Efimovich Vol'pin 1
Mark Efimovich Vol'pin
10.1070/MC1997v007n02ABEH000679
Published 1997-04-30
Communication , Volume 7, Issue 2, 61-63
8
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Orlinkov A. V. et al. Alkylation of deactivated arenes by alkanes in the presence of aprotic organic superacid CBr4·2AlBr3 // Mendeleev Communications. 1997. Vol. 7. No. 2. pp. 61-63.
GOST all authors (up to 50) Copy
Orlinkov A. V., Akhrem I. S., Afanas'eva L. V., Mysov E. I., Vol'pin M. E. Alkylation of deactivated arenes by alkanes in the presence of aprotic organic superacid CBr4·2AlBr3 // Mendeleev Communications. 1997. Vol. 7. No. 2. pp. 61-63.
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TY - JOUR
DO - 10.1070/MC1997v007n02ABEH000679
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000679
TI - Alkylation of deactivated arenes by alkanes in the presence of aprotic organic superacid CBr4·2AlBr3
T2 - Mendeleev Communications
AU - Orlinkov, Alexander Vyacheslavovich
AU - Akhrem, Irena Sergeevna
AU - Afanas'eva, Lyudmila Vyacheslavovna
AU - Mysov, Eugeny Ivanovich
AU - Vol'pin, Mark Efimovich
PY - 1997
DA - 1997/04/30
PB - Mendeleev Communications
SP - 61-63
IS - 2
VL - 7
ER -
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@article{1997_Orlinkov,
author = {Alexander Vyacheslavovich Orlinkov and Irena Sergeevna Akhrem and Lyudmila Vyacheslavovna Afanas'eva and Eugeny Ivanovich Mysov and Mark Efimovich Vol'pin},
title = {Alkylation of deactivated arenes by alkanes in the presence of aprotic organic superacid CBr4·2AlBr3},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000679},
number = {2},
pages = {61--63},
doi = {10.1070/MC1997v007n02ABEH000679}
}
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Orlinkov, Alexander Vyacheslavovich, et al. “Alkylation of deactivated arenes by alkanes in the presence of aprotic organic superacid CBr4·2AlBr3.” Mendeleev Communications, vol. 7, no. 2, Apr. 1997, pp. 61-63. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000679.

Abstract

Deactivated arenes (di- and tri-halobenzenes, acetophenone, benzophenone and methylbenzoate) have been shown to be alkylated by alkanes and cycloalkanes (propane, n-butane, cyclopentane) in the presence of superacid CBr4·2AlBr3 in the range –40 to 0 °C; in some cases selective and effective mono- or di-alkylation can be achieved.

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