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1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring

Galina Anatol'evna Dushenko 1
Galina Anatol'evna Dushenko
, 
Igor Evguen'evich Mikhailov 1
Igor Evguen'evich Mikhailov
, 
Adolf Zschunke 2
Adolf Zschunke
, 
Nils Hakam 3
Nils Hakam
, 
Clemens Muegge 3
Clemens Muegge
, 
Vladimir Isaakovich Minkin 1
Vladimir Isaakovich Minkin
10.1070/MC1997v007n02ABEH000669
Published 1997-04-30
Communication , Volume 7, Issue 2, 50-51
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Dushenko G. A. et al. 1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring // Mendeleev Communications. 1997. Vol. 7. No. 2. pp. 50-51.
GOST all authors (up to 50) Copy
Dushenko G. A., Mikhailov I. E., Zschunke A., Hakam N., Muegge C., Minkin V. I. 1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring // Mendeleev Communications. 1997. Vol. 7. No. 2. pp. 50-51.
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TY - JOUR
DO - 10.1070/MC1997v007n02ABEH000669
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000669
TI - 1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring
T2 - Mendeleev Communications
AU - Dushenko, Galina Anatol'evna
AU - Mikhailov, Igor Evguen'evich
AU - Zschunke, Adolf
AU - Hakam, Nils
AU - Muegge, Clemens
AU - Minkin, Vladimir Isaakovich
PY - 1997
DA - 1997/04/30
PB - Mendeleev Communications
SP - 50-51
IS - 2
VL - 7
ER -
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@article{1997_Dushenko,
author = {Galina Anatol'evna Dushenko and Igor Evguen'evich Mikhailov and Adolf Zschunke and Nils Hakam and Clemens Muegge and Vladimir Isaakovich Minkin},
title = {1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000669},
number = {2},
pages = {50--51},
doi = {10.1070/MC1997v007n02ABEH000669}
}
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Dushenko, Galina Anatol'evna, et al. “1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring.” Mendeleev Communications, vol. 7, no. 2, Apr. 1997, pp. 50-51. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n02ABEH000669.

Abstract

Rapid and reversible migrations of the phenylsulfanyl group around the seven-membered ring of 7-phenylsulfanylcyclohepta- 1,3,5-triene have been proved to proceed through successive 1,7-sigmatropic shifts with an energy barrier (ΔG≠298) in the range of 19.5−20.1 kcal mol–1.

References

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