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Facile hydrogen-transfer reduction of multiple bonds by formic acid catalysed with a Pd-561 giant cluster

Ilya Iosifovich Moiseev 1
Ilya Iosifovich Moiseev
, 
Gennadii A Tsirkov 1
Gennadii A Tsirkov
, 
Alexander Efimovitch Gekhman 1
Alexander Efimovitch Gekhman
, 
Michael Natanovich Vargaftik 1
Michael Natanovich Vargaftik
10.1070/MC1997v007n01ABEH000696
Published 1997-02-28
Communication , Volume 7, Issue 1, 1-3
9
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Moiseev I. I. et al. Facile hydrogen-transfer reduction of multiple bonds by formic acid catalysed with a Pd-561 giant cluster // Mendeleev Communications. 1997. Vol. 7. No. 1. pp. 1-3.
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Moiseev I. I., Tsirkov G. A., Gekhman A. E., Vargaftik M. N. Facile hydrogen-transfer reduction of multiple bonds by formic acid catalysed with a Pd-561 giant cluster // Mendeleev Communications. 1997. Vol. 7. No. 1. pp. 1-3.
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TY - JOUR
DO - 10.1070/MC1997v007n01ABEH000696
UR - https://mendcomm.colab.ws/publications/10.1070/MC1997v007n01ABEH000696
TI - Facile hydrogen-transfer reduction of multiple bonds by formic acid catalysed with a Pd-561 giant cluster
T2 - Mendeleev Communications
AU - Moiseev, Ilya Iosifovich
AU - Tsirkov, Gennadii A
AU - Gekhman, Alexander Efimovitch
AU - Vargaftik, Michael Natanovich
PY - 1997
DA - 1997/02/28
PB - Mendeleev Communications
SP - 1-3
IS - 1
VL - 7
ER -
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@article{1997_Moiseev,
author = {Ilya Iosifovich Moiseev and Gennadii A Tsirkov and Alexander Efimovitch Gekhman and Michael Natanovich Vargaftik},
title = {Facile hydrogen-transfer reduction of multiple bonds by formic acid catalysed with a Pd-561 giant cluster},
journal = {Mendeleev Communications},
year = {1997},
volume = {7},
publisher = {Mendeleev Communications},
month = {Feb},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1997v007n01ABEH000696},
number = {1},
pages = {1--3},
doi = {10.1070/MC1997v007n01ABEH000696}
}
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Moiseev, Ilya Iosifovich, et al. “Facile hydrogen-transfer reduction of multiple bonds by formic acid catalysed with a Pd-561 giant cluster.” Mendeleev Communications, vol. 7, no. 1, Feb. 1997, pp. 1-3. https://mendcomm.colab.ws/publications/10.1070/MC1997v007n01ABEH000696.

Abstract

A palladium-561 giant cluster/HCOOH hydrogen-transfer reduction system has been found to be efficient for the liquid-phase hydrogenation of aromatic and aliphatic compounds with N=O, C≡N, C=O and C=C bonds under mild conditions; the reduction of nitriles is accompanied by metathesis of amines under unusually mild conditions.

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