Home / Publications / The unusual reaction of [8-(dimethylamino)methyl-1-naphthyl]phenylchlorosilane with fluoren-9-yllithium. Synthesis of kinetically stable dibenzosilafulvene

The unusual reaction of [8-(dimethylamino)methyl-1-naphthyl]phenylchlorosilane with fluoren-9-yllithium. Synthesis of kinetically stable dibenzosilafulvene

Irina V Borisova 1
Irina V Borisova
, 
Nikolai Nikolaevich Zemlyansky 1
Nikolai Nikolaevich Zemlyansky
, 
Alla Konstantinovna Shestakova 1
Alla Konstantinovna Shestakova
, 
Yuri Aleksandrovich Ustynyuk 2
Yuri Aleksandrovich Ustynyuk
10.1070/MC1996v006n06ABEH000736
Published 1996-12-31
Communication , Volume 6, Issue 6, 229-230
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Borisova I. V. et al. The unusual reaction of [8-(dimethylamino)methyl-1-naphthyl]phenylchlorosilane with fluoren-9-yllithium. Synthesis of kinetically stable dibenzosilafulvene // Mendeleev Communications. 1996. Vol. 6. No. 6. pp. 229-230.
GOST all authors (up to 50) Copy
Borisova I. V., Zemlyansky N. N., Shestakova A. K., Ustynyuk Y. A. The unusual reaction of [8-(dimethylamino)methyl-1-naphthyl]phenylchlorosilane with fluoren-9-yllithium. Synthesis of kinetically stable dibenzosilafulvene // Mendeleev Communications. 1996. Vol. 6. No. 6. pp. 229-230.
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TY - JOUR
DO - 10.1070/MC1996v006n06ABEH000736
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n06ABEH000736
TI - The unusual reaction of [8-(dimethylamino)methyl-1-naphthyl]phenylchlorosilane with fluoren-9-yllithium. Synthesis of kinetically stable dibenzosilafulvene
T2 - Mendeleev Communications
AU - Borisova, Irina V
AU - Zemlyansky, Nikolai Nikolaevich
AU - Shestakova, Alla Konstantinovna
AU - Ustynyuk, Yuri Aleksandrovich
PY - 1996
DA - 1996/12/31
PB - Mendeleev Communications
SP - 229-230
IS - 6
VL - 6
ER -
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@article{1996_Borisova,
author = {Irina V Borisova and Nikolai Nikolaevich Zemlyansky and Alla Konstantinovna Shestakova and Yuri Aleksandrovich Ustynyuk},
title = {The unusual reaction of [8-(dimethylamino)methyl-1-naphthyl]phenylchlorosilane with fluoren-9-yllithium. Synthesis of kinetically stable dibenzosilafulvene},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n06ABEH000736},
number = {6},
pages = {229--230},
doi = {10.1070/MC1996v006n06ABEH000736}
}
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Cite this
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Borisova, Irina V., et al. “The unusual reaction of [8-(dimethylamino)methyl-1-naphthyl]phenylchlorosilane with fluoren-9-yllithium. Synthesis of kinetically stable dibenzosilafulvene.” Mendeleev Communications, vol. 6, no. 6, Dec. 1996, pp. 229-230. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n06ABEH000736.

Abstract

The first stable dibenzosilafulvene, 14-[8’-(dimethylamino)metliyl-l’-naplitliyl]-14-plienyl-14-silafluorenylide 1, was obtained in one step from fluoren-9-yllithium and [8-(dimethylamino)methyl-l-naphthyl]phenylchlorosilane 2 as a stable solvate with THF; the zwitterionic structure of 1 is established by 1H, 13C and 29Si NMR in solution and solid state and its reactions with crotonaldehyde, ethanol and triethylethylidene-λ5-phosphane are described.

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