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Enantioselectivity of the PPL-catalysed hydrolysis of racemic esters: some cases implying a conformational substrate model

Edward Prokof'evich Serebryakov 1
Edward Prokof'evich Serebryakov
, 
Galina Dmitrievna Gamalevich 1
Galina Dmitrievna Gamalevich
10.1070/MC1996v006n06ABEH000733
Published 1996-12-31
Communication , Volume 6, Issue 6, 221-224
3
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Serebryakov E. P., Gamalevich G. D. Enantioselectivity of the PPL-catalysed hydrolysis of racemic esters: some cases implying a conformational substrate model // Mendeleev Communications. 1996. Vol. 6. No. 6. pp. 221-224.
GOST all authors (up to 50) Copy
Serebryakov E. P., Gamalevich G. D. Enantioselectivity of the PPL-catalysed hydrolysis of racemic esters: some cases implying a conformational substrate model // Mendeleev Communications. 1996. Vol. 6. No. 6. pp. 221-224.
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TY - JOUR
DO - 10.1070/MC1996v006n06ABEH000733
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n06ABEH000733
TI - Enantioselectivity of the PPL-catalysed hydrolysis of racemic esters: some cases implying a conformational substrate model
T2 - Mendeleev Communications
AU - Serebryakov, Edward Prokof'evich
AU - Gamalevich, Galina Dmitrievna
PY - 1996
DA - 1996/12/31
PB - Mendeleev Communications
SP - 221-224
IS - 6
VL - 6
ER -
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@article{1996_Serebryakov,
author = {Edward Prokof'evich Serebryakov and Galina Dmitrievna Gamalevich},
title = {Enantioselectivity of the PPL-catalysed hydrolysis of racemic esters: some cases implying a conformational substrate model},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Dec},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n06ABEH000733},
number = {6},
pages = {221--224},
doi = {10.1070/MC1996v006n06ABEH000733}
}
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Serebryakov, Edward Prokof'evich, and Galina Dmitrievna Gamalevich. “Enantioselectivity of the PPL-catalysed hydrolysis of racemic esters: some cases implying a conformational substrate model.” Mendeleev Communications, vol. 6, no. 6, Dec. 1996, pp. 221-224. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n06ABEH000733.

Abstract

The dependence of the PPL-mediated optical resolution of eighteen racemic esters on the substrate's structure (the sense and magnitude of enantioselectivity, or the inertness of certain substrates) appears to be best explained by a mechanistic model involving a W-shaped active conformation of the substrate laying in a diastereodiscriminating plane.

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