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Influence of tunnelling on the ratio of the activation rate constants of C–C and C–H bonds in ethane by a bare palladium atom

Viktor Mikhailovich Mamaev 1
Viktor Mikhailovich Mamaev
,  , 
Andrei Viktorovich Prisyajnuk 2
Andrei Viktorovich Prisyajnuk
, 
Yuri Aleksandrovich Ustynyuk 1
Yuri Aleksandrovich Ustynyuk
10.1070/MC1996v006n05ABEH000647
Published 1996-10-30
Communication , Volume 6, Issue 5, 203-205
5
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Mamaev V. M. et al. Influence of tunnelling on the ratio of the activation rate constants of C–C and C–H bonds in ethane by a bare palladium atom // Mendeleev Communications. 1996. Vol. 6. No. 5. pp. 203-205.
GOST all authors (up to 50) Copy
Mamaev V. M., Gloriozov I. P., Prisyajnuk A. V., Ustynyuk Y. A. Influence of tunnelling on the ratio of the activation rate constants of C–C and C–H bonds in ethane by a bare palladium atom // Mendeleev Communications. 1996. Vol. 6. No. 5. pp. 203-205.
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TY - JOUR
DO - 10.1070/MC1996v006n05ABEH000647
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000647
TI - Influence of tunnelling on the ratio of the activation rate constants of C–C and C–H bonds in ethane by a bare palladium atom
T2 - Mendeleev Communications
AU - Mamaev, Viktor Mikhailovich
AU - Gloriozov, Igor Pavlovich
AU - Prisyajnuk, Andrei Viktorovich
AU - Ustynyuk, Yuri Aleksandrovich
PY - 1996
DA - 1996/10/30
PB - Mendeleev Communications
SP - 203-205
IS - 5
VL - 6
ER -
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@article{1996_Mamaev,
author = {Viktor Mikhailovich Mamaev and Igor Pavlovich Gloriozov and Andrei Viktorovich Prisyajnuk and Yuri Aleksandrovich Ustynyuk},
title = {Influence of tunnelling on the ratio of the activation rate constants of C–C and C–H bonds in ethane by a bare palladium atom},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000647},
number = {5},
pages = {203--205},
doi = {10.1070/MC1996v006n05ABEH000647}
}
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Mamaev, Viktor Mikhailovich, et al. “Influence of tunnelling on the ratio of the activation rate constants of C–C and C–H bonds in ethane by a bare palladium atom.” Mendeleev Communications, vol. 6, no. 5, Oct. 1996, pp. 203-205. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000647.

Abstract

Dynamic modeling of ethane oxidative insertion to a bare palladium atom at both C–C and C–H bonds has demonstrated the influence of quantum effects in the more growth of the rate constant of C–H bond activation compared to C–C activation.

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