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Five oxidation states in metal-bonded C4 chains

Michael I Bruce 1
Michael I Bruce
, 
Larisa Ivanovna Denisovich 2
Larisa Ivanovna Denisovich
, 
Paul J Low 1
Paul J Low
, 
Svetlana Mikhailovna Peregudova 2
Svetlana Mikhailovna Peregudova
, 
Nikolai Aleksandrovich Ustynyuk 2
Nikolai Aleksandrovich Ustynyuk
10.1070/MC1996v006n05ABEH000645
Published 1996-10-30
Communication , Volume 6, Issue 5, 200-201
45
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Bruce M. I. et al. Five oxidation states in metal-bonded C4 chains // Mendeleev Communications. 1996. Vol. 6. No. 5. pp. 200-201.
GOST all authors (up to 50) Copy
Bruce M. I., Denisovich L. I., Low P. J., Peregudova S. M., Ustynyuk N. A. Five oxidation states in metal-bonded C4 chains // Mendeleev Communications. 1996. Vol. 6. No. 5. pp. 200-201.
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TY - JOUR
DO - 10.1070/MC1996v006n05ABEH000645
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000645
TI - Five oxidation states in metal-bonded C4 chains
T2 - Mendeleev Communications
AU - Bruce, Michael I
AU - Denisovich, Larisa Ivanovna
AU - Low, Paul J
AU - Peregudova, Svetlana Mikhailovna
AU - Ustynyuk, Nikolai Aleksandrovich
PY - 1996
DA - 1996/10/30
PB - Mendeleev Communications
SP - 200-201
IS - 5
VL - 6
ER -
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@article{1996_Bruce,
author = {Michael I Bruce and Larisa Ivanovna Denisovich and Paul J Low and Svetlana Mikhailovna Peregudova and Nikolai Aleksandrovich Ustynyuk},
title = {Five oxidation states in metal-bonded C4 chains},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000645},
number = {5},
pages = {200--201},
doi = {10.1070/MC1996v006n05ABEH000645}
}
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Bruce, Michael I., et al. “Five oxidation states in metal-bonded C4 chains.” Mendeleev Communications, vol. 6, no. 5, Oct. 1996, pp. 200-201. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000645.

Abstract

The 36-electron diruthenium buta-l,3-diynyl complexes [Ru]C ≡ C–C ≡ C[Ru] [Ru = Ru(PPh3)2Cp and Ru(PMe3)(PPh3)Cp] undergo four stepwise one-electron oxidation–reduction processes by cyclic voltammetry; some of the oxidised complexes have also been prepared by chemical oxidation.

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