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Layered polyhydrate 18-crown-6C3H7NH3F.10H2O

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Udachin K. A., Lipkowski J. Layered polyhydrate 18-crown-6C3H7NH3F.10H2O // Mendeleev Communications. 1996. Vol. 6. No. 5. pp. 195-197.
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Udachin K. A., Lipkowski J. Layered polyhydrate 18-crown-6C3H7NH3F.10H2O // Mendeleev Communications. 1996. Vol. 6. No. 5. pp. 195-197.
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TY - JOUR
DO - 10.1070/MC1996v006n05ABEH000643
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000643
TI - Layered polyhydrate 18-crown-6C3H7NH3F.10H2O
T2 - Mendeleev Communications
AU - Udachin, Konstantin Anatol'evich
AU - Lipkowski, Janusz
PY - 1996
DA - 1996/10/30
PB - Mendeleev Communications
SP - 195-197
IS - 5
VL - 6
ER -
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@article{1996_Udachin,
author = {Konstantin Anatol'evich Udachin and Janusz Lipkowski},
title = {Layered polyhydrate 18-crown-6C3H7NH3F.10H2O},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000643},
number = {5},
pages = {195--197},
doi = {10.1070/MC1996v006n05ABEH000643}
}
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Udachin, Konstantin Anatol'evich, and Janusz Lipkowski. “Layered polyhydrate 18-crown-6C3H7NH3F.10H2O.” Mendeleev Communications, vol. 6, no. 5, Oct. 1996, pp. 195-197. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000643.

Abstract

New polyhydrate 18-crown-6C3H7NH3F-10H2O which melts incongruently at —0.8̊C has been found in the 18-crown-6-C3H7NH3F-H2O system; a single crystal X-ray structure of this layered hydrate is reported, in which layers of water molecules and fluoride anions are made up of tetra-, penta- and heptagons and also contain vacant polyhedral cavities; the crown ether complexes with cations C3H7NH3 + are situated between water-fluoride layers and do not form hydrogen bonds with the molecules of the layers.

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