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Layered polyhydrate 15-crown-5·8H20

Konstantin Anatol'evich Udachin 1
Konstantin Anatol'evich Udachin
, 
Janusz Lipkowski 2
Janusz Lipkowski
10.1070/MC1996v006n05ABEH000642
Published 1996-10-30
Communication , Volume 6, Issue 5, 197-198
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Udachin K. A., Lipkowski J. Layered polyhydrate 15-crown-5·8H20 // Mendeleev Communications. 1996. Vol. 6. No. 5. pp. 197-198.
GOST all authors (up to 50) Copy
Udachin K. A., Lipkowski J. Layered polyhydrate 15-crown-5·8H20 // Mendeleev Communications. 1996. Vol. 6. No. 5. pp. 197-198.
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TY - JOUR
DO - 10.1070/MC1996v006n05ABEH000642
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000642
TI - Layered polyhydrate 15-crown-5·8H20
T2 - Mendeleev Communications
AU - Udachin, Konstantin Anatol'evich
AU - Lipkowski, Janusz
PY - 1996
DA - 1996/10/30
PB - Mendeleev Communications
SP - 197-198
IS - 5
VL - 6
ER -
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@article{1996_Udachin,
author = {Konstantin Anatol'evich Udachin and Janusz Lipkowski},
title = {Layered polyhydrate 15-crown-5·8H20},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Oct},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000642},
number = {5},
pages = {197--198},
doi = {10.1070/MC1996v006n05ABEH000642}
}
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Udachin, Konstantin Anatol'evich, and Janusz Lipkowski. “Layered polyhydrate 15-crown-5·8H20.” Mendeleev Communications, vol. 6, no. 5, Oct. 1996, pp. 197-198. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n05ABEH000642.

Abstract

The phase diagram of the system 15-crown-5–H2O, has been studied, and the polyhydrate 15-crown-5•8H2O, which melts congruently at 12.8 °C, has been found; a single crystal X-ray structure of the novel layered polyhydrate 15-crown-5·8H2O is reported, which shows that water molecules connected via hydrogen bonds, forming pentagons and octagons make up layers, and the crown ether molecules are situated between water layers, forming hydrogen bonds with water molecules of the layers.

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