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Synthetic nucleases triggered by mild acidification: a new type of biologically active compounds

Ilia Yakovlevich Levitin 1
Ilia Yakovlevich Levitin
, 
Vladimir Mikhailovich Belkov 1
Vladimir Mikhailovich Belkov
, 
Galina Nikolaevna Novodarova 1
Galina Nikolaevna Novodarova
, 
Zoya Alekseevna Shabarova 2
Zoya Alekseevna Shabarova
, 
Mark Efimovich Vol'pin 1
Mark Efimovich Vol'pin
10.1070/MC1996v006n04ABEH000624
Published 1996-08-31
Communication , Volume 6, Issue 4, 153-154
4
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Levitin I. Y. et al. Synthetic nucleases triggered by mild acidification: a new type of biologically active compounds // Mendeleev Communications. 1996. Vol. 6. No. 4. pp. 153-154.
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Levitin I. Y., Belkov V. M., Novodarova G. N., Shabarova Z. A., Vol'pin M. E. Synthetic nucleases triggered by mild acidification: a new type of biologically active compounds // Mendeleev Communications. 1996. Vol. 6. No. 4. pp. 153-154.
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TY - JOUR
DO - 10.1070/MC1996v006n04ABEH000624
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n04ABEH000624
TI - Synthetic nucleases triggered by mild acidification: a new type of biologically active compounds
T2 - Mendeleev Communications
AU - Levitin, Ilia Yakovlevich
AU - Belkov, Vladimir Mikhailovich
AU - Novodarova, Galina Nikolaevna
AU - Shabarova, Zoya Alekseevna
AU - Vol'pin, Mark Efimovich
PY - 1996
DA - 1996/08/31
PB - Mendeleev Communications
SP - 153-154
IS - 4
VL - 6
ER -
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@article{1996_Levitin,
author = {Ilia Yakovlevich Levitin and Vladimir Mikhailovich Belkov and Galina Nikolaevna Novodarova and Zoya Alekseevna Shabarova and Mark Efimovich Vol'pin},
title = {Synthetic nucleases triggered by mild acidification: a new type of biologically active compounds},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Aug},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n04ABEH000624},
number = {4},
pages = {153--154},
doi = {10.1070/MC1996v006n04ABEH000624}
}
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Levitin, Ilia Yakovlevich, et al. “Synthetic nucleases triggered by mild acidification: a new type of biologically active compounds.” Mendeleev Communications, vol. 6, no. 4, Aug. 1996, pp. 153-154. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n04ABEH000624.

Abstract

Alkylcobalt chelates possessing tridentate Schiff bases display nuclease activity upon proton-assisted homolytic decomposition, due to the formation of both alkyl free radicals and a cobalt complex catalysing the autooxidation of organic substrates.

References

1.
Ready homolytic splitting of an organocobalt(III) complex under the action of protons: new sources of free radicals
Levitin I.Y., Sigan A.L., Bodnar R.M., Gasanov R.G., Vol'pin M.E.
Inorganica Chimica Acta, 1983
2.
Kinetics and mechanism of acid-induced homolysis of the metal—carbon bond in organocobalt(III) chelates with a tridentate ligand
Ryabov A.D., Levitin I.Y., Nikitaev A.T., Kitaigorodskii A.N., Bakhmutov V.I., Gromov I.Y., Yatsimirsky A.K., Vol'pin M.E.
Journal of Organometallic Chemistry, 1985
3.
10.1070/MC1996v006n04ABEH000624_bib3
Levitin
Metalloorg. Khim., 1990