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Molecular mechanism of alkane oxidation involving binuclear iron complexes

Vera Sergeevna Kulikova 1
Vera Sergeevna Kulikova
, 
Olga Nikolaevna Gritsenko 1
Olga Nikolaevna Gritsenko
, 
Al'bert Aleksandrovich Shteinman 1
Al'bert Aleksandrovich Shteinman
10.1070/MC1996v006n03ABEH000608
Published 1996-06-30
Communication , Volume 6, Issue 3, 119-120
30
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Kulikova V. S., Gritsenko O. N., Shteinman A. A. Molecular mechanism of alkane oxidation involving binuclear iron complexes // Mendeleev Communications. 1996. Vol. 6. No. 3. pp. 119-120.
GOST all authors (up to 50) Copy
Kulikova V. S., Gritsenko O. N., Shteinman A. A. Molecular mechanism of alkane oxidation involving binuclear iron complexes // Mendeleev Communications. 1996. Vol. 6. No. 3. pp. 119-120.
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TY - JOUR
DO - 10.1070/MC1996v006n03ABEH000608
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n03ABEH000608
TI - Molecular mechanism of alkane oxidation involving binuclear iron complexes
T2 - Mendeleev Communications
AU - Kulikova, Vera Sergeevna
AU - Gritsenko, Olga Nikolaevna
AU - Shteinman, Al'bert Aleksandrovich
PY - 1996
DA - 1996/06/30
PB - Mendeleev Communications
SP - 119-120
IS - 3
VL - 6
ER -
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@article{1996_Kulikova,
author = {Vera Sergeevna Kulikova and Olga Nikolaevna Gritsenko and Al'bert Aleksandrovich Shteinman},
title = {Molecular mechanism of alkane oxidation involving binuclear iron complexes},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n03ABEH000608},
number = {3},
pages = {119--120},
doi = {10.1070/MC1996v006n03ABEH000608}
}
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Kulikova, Vera Sergeevna, et al. “Molecular mechanism of alkane oxidation involving binuclear iron complexes.” Mendeleev Communications, vol. 6, no. 3, Jun. 1996, pp. 119-120. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n03ABEH000608.

Abstract

The use of substrate probes for establishing the nature of intermediates and the mechanism of alkane oxidation by peroxides upon catalysis by binuclear iron complexes {[Fe2OL2 (H2O)2](ClO4)4, where L = bpy, 4,4′-Me2bpy or 5-NO2phen (bpy = bipyridine, phen = phenanthroline)}, the analysis of the dependence of test parameters on the nature of a substituent in a ligand and the effect of dioxygen all make it possible to diagnose a two-electron mechanism for the transfer of the oxygen atom from peroxide to the C–H bond of an alkane via metal complexes.

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