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Channel polyhydrate (C2H5)4NF.11H2O

Konstantin Anatol'evich Udachin 1
Konstantin Anatol'evich Udachin
, 
Janusz Lipkowski 2
Janusz Lipkowski
10.1070/MC1996v006n03ABEH000593
Published 1996-06-30
Communication , Volume 6, Issue 3, 92-93
9
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Udachin K. A., Lipkowski J. Channel polyhydrate (C2H5)4NF.11H2O // Mendeleev Communications. 1996. Vol. 6. No. 3. pp. 92-93.
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Udachin K. A., Lipkowski J. Channel polyhydrate (C2H5)4NF.11H2O // Mendeleev Communications. 1996. Vol. 6. No. 3. pp. 92-93.
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TY - JOUR
DO - 10.1070/MC1996v006n03ABEH000593
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n03ABEH000593
TI - Channel polyhydrate (C2H5)4NF.11H2O
T2 - Mendeleev Communications
AU - Udachin, Konstantin Anatol'evich
AU - Lipkowski, Janusz
PY - 1996
DA - 1996/06/30
PB - Mendeleev Communications
SP - 92-93
IS - 3
VL - 6
ER -
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@article{1996_Udachin,
author = {Konstantin Anatol'evich Udachin and Janusz Lipkowski},
title = {Channel polyhydrate (C2H5)4NF.11H2O},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Jun},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n03ABEH000593},
number = {3},
pages = {92--93},
doi = {10.1070/MC1996v006n03ABEH000593}
}
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Udachin, Konstantin Anatol'evich, and Janusz Lipkowski. “Channel polyhydrate (C2H5)4NF.11H2O.” Mendeleev Communications, vol. 6, no. 3, Jun. 1996, pp. 92-93. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n03ABEH000593.

Abstract

The phase diagram of the system (C2H5)4NF–H2O, has been studied. The polyhydrates (C2H5)4NF·5H2O and (C2H5)4NF·11H2O, which melt congruently at 24.8 and – 13.6 °C respectively, have been found in this system. The hydrate (C2H5)4NF-11H2O has a channel–cavity structure. Water and fluoride anions form a three-dimensional framework consisting of channels and cavities. The channels are filled with cations (C2H5)4N+, and the cavities are vacant. The polyhydrate (C2H5)4NF·11H2O has the following crystallographic parameters: a = 12.393(3), b = 22.595(7) c = 11.483(3) A (T = –100°C), space group Pnnm, Z = 6.

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