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Mild selective metathesis of alkane C–H bonds and C–X bonds of polyhalogenomethane CH4–nXn (X = Cl, n = 4; Br, I, n = 3) catalysed with chlorotris(triphenylphosphine)rhodium(I)

Andrei Nikolaevich Vedernikov 1
Andrei Nikolaevich Vedernikov
, 
Rafael Rivkhatovich Sharifullin 1
Rafael Rivkhatovich Sharifullin
, 
Boris Nikolaevich Solomonov 1
Boris Nikolaevich Solomonov
10.1070/MC1996v006n02ABEH000577
Published 1996-04-30
Communication , Volume 6, Issue 2, 54-55
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Vedernikov A. N., Sharifullin R. R., Solomonov B. N. Mild selective metathesis of alkane C–H bonds and C–X bonds of polyhalogenomethane CH4–nXn (X = Cl, n = 4; Br, I, n = 3) catalysed with chlorotris(triphenylphosphine)rhodium(I) // Mendeleev Communications. 1996. Vol. 6. No. 2. pp. 54-55.
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Vedernikov A. N., Sharifullin R. R., Solomonov B. N. Mild selective metathesis of alkane C–H bonds and C–X bonds of polyhalogenomethane CH4–nXn (X = Cl, n = 4; Br, I, n = 3) catalysed with chlorotris(triphenylphosphine)rhodium(I) // Mendeleev Communications. 1996. Vol. 6. No. 2. pp. 54-55.
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TY - JOUR
DO - 10.1070/MC1996v006n02ABEH000577
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000577
TI - Mild selective metathesis of alkane C–H bonds and C–X bonds of polyhalogenomethane CH4–nXn (X = Cl, n = 4; Br, I, n = 3) catalysed with chlorotris(triphenylphosphine)rhodium(I)
T2 - Mendeleev Communications
AU - Vedernikov, Andrei Nikolaevich
AU - Sharifullin, Rafael Rivkhatovich
AU - Solomonov, Boris Nikolaevich
PY - 1996
DA - 1996/04/30
PB - Mendeleev Communications
SP - 54-55
IS - 2
VL - 6
ER -
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@article{1996_Vedernikov,
author = {Andrei Nikolaevich Vedernikov and Rafael Rivkhatovich Sharifullin and Boris Nikolaevich Solomonov},
title = {Mild selective metathesis of alkane C–H bonds and C–X bonds of polyhalogenomethane CH4–nXn (X = Cl, n = 4; Br, I, n = 3) catalysed with chlorotris(triphenylphosphine)rhodium(I)},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000577},
number = {2},
pages = {54--55},
doi = {10.1070/MC1996v006n02ABEH000577}
}
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Vedernikov, Andrei Nikolaevich, et al. “Mild selective metathesis of alkane C–H bonds and C–X bonds of polyhalogenomethane CH4–nXn (X = Cl, n = 4; Br, I, n = 3) catalysed with chlorotris(triphenylphosphine)rhodium(I).” Mendeleev Communications, vol. 6, no. 2, Apr. 1996, pp. 54-55. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000577.

Abstract

Alkanes RH (n-C6H14, cyclo-C6H12) and toluene react with polyhalogenomethanes CC14, CHBr3 and CHI3 at 80–110 °C under catalysis with Wilkinson's complex, RhCl(PPh3)3, to produce halogenohydrocarbons RX and CHC13, CH2Br2 or CH2I2 respectively with unusually high selectivity which decreases in the order: C–Hsecondary > > C–Hbenzyiic > C–Hprimary.

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