Home / Publications / Synthesis and X-ray crystal structure of l-cyano-3,3-bis(trifluoromethyl)-l,3-dihydro-lλ3,2-benzoiodoxole, a stable cyanoiodolane

Synthesis and X-ray crystal structure of l-cyano-3,3-bis(trifluoromethyl)-l,3-dihydro-lλ3,2-benzoiodoxole, a stable cyanoiodolane

, 
Chris J Kuehl 1
Chris J Kuehl
, 
Atta M Arif 2
Atta M Arif
, 
Peter J Stang 2
Peter J Stang
10.1070/MC1996v006n02ABEH000575
Published 1996-04-30
Communication , Volume 6, Issue 2, 50-51
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Zhdankin V. V. et al. Synthesis and X-ray crystal structure of l-cyano-3,3-bis(trifluoromethyl)-l,3-dihydro-lλ3,2-benzoiodoxole, a stable cyanoiodolane // Mendeleev Communications. 1996. Vol. 6. No. 2. pp. 50-51.
GOST all authors (up to 50) Copy
Zhdankin V. V., Kuehl C. J., Arif A. M., Stang P. J. Synthesis and X-ray crystal structure of l-cyano-3,3-bis(trifluoromethyl)-l,3-dihydro-lλ3,2-benzoiodoxole, a stable cyanoiodolane // Mendeleev Communications. 1996. Vol. 6. No. 2. pp. 50-51.
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TY - JOUR
DO - 10.1070/MC1996v006n02ABEH000575
UR - https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000575
TI - Synthesis and X-ray crystal structure of l-cyano-3,3-bis(trifluoromethyl)-l,3-dihydro-lλ3,2-benzoiodoxole, a stable cyanoiodolane
T2 - Mendeleev Communications
AU - Zhdankin, Viktor Vladimirovich
AU - Kuehl, Chris J
AU - Arif, Atta M
AU - Stang, Peter J
PY - 1996
DA - 1996/04/30
PB - Mendeleev Communications
SP - 50-51
IS - 2
VL - 6
ER -
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@article{1996_Zhdankin,
author = {Viktor Vladimirovich Zhdankin and Chris J Kuehl and Atta M Arif and Peter J Stang},
title = {Synthesis and X-ray crystal structure of l-cyano-3,3-bis(trifluoromethyl)-l,3-dihydro-lλ3,2-benzoiodoxole, a stable cyanoiodolane},
journal = {Mendeleev Communications},
year = {1996},
volume = {6},
publisher = {Mendeleev Communications},
month = {Apr},
url = {https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000575},
number = {2},
pages = {50--51},
doi = {10.1070/MC1996v006n02ABEH000575}
}
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Zhdankin, Viktor Vladimirovich, et al. “Synthesis and X-ray crystal structure of l-cyano-3,3-bis(trifluoromethyl)-l,3-dihydro-lλ3,2-benzoiodoxole, a stable cyanoiodolane.” Mendeleev Communications, vol. 6, no. 2, Apr. 1996, pp. 50-51. https://mendcomm.colab.ws/publications/10.1070/MC1996v006n02ABEH000575.

Abstract

Stable, crystalline cyanoiodolane 3 has been prepared in two steps by sequential reactions of l-hydroxy-3,3-bis(trifluoromethyl)-l,3-dihydro-lλ3,2-benzoiodoxole 1 with trimethylsilyltriflate and then with cyanotrimethysilane; X-ray structure analysis reveals a distorted T-shaped structure for iodine with an endocyclic I-O bond distance of 2.117 A, which is significantly shorter than usual in C-substituted benzoiodoxole derivatives.

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